Hydrophilic Interpolymer Associates as a Satellite Product of Reactions of Formation of Interpolymer Complexes

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It is shown, that reaction between polyacrylic acid and polyvinyl caprolactam leads to formation of wide range of different products. Besides classic interpolymer complexes and physically cross-linked hydrogels, the intermediates are formed. Those intermediates, particularly, include hydrophilic interpolymer associates, i.e. semistable polymer networks existing in dynamical mode, which is characterized by continuous process of formation/destroying of hydrogen bonds. Other intermediate products are relatively stable fragments of the polymer networks or associates stabilized by hydrogen bonds.

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58-63

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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