Morphology and Strength of Cement Paste from Clay as Nanomaterial

Article Preview

Abstract:

Now days the application of nanomaterials was vastly growing in the development of new material to improve the quality of human life. Particles of nanomaterials which are in nanoscale helps to improve to the characteristics of the existing micro based materials. The application of nanomaterials in the construction were started since in the early 90s when during those time micro based materials was very demanding especially when dealing with High Performance Concrete (HPC). The utilization of nanobased materials improves and reinforces the cement matrix system and performs early strength and also enhances tensile properties of concrete. In this research, two types of clay were used which nanometakaolin and nanometaclay. nanometakaolin were made from sol gel process thats involved milling technique and nanometaclay were supplied by Sigma Aldrich. The mix proportion for clay based cement paste also includes metakaolin as cement replacement material. nanometakaolin and nanometaclay was added as additives from 0, 1, 3, 5, 7, 9 percent (%) from weight of cement and will be compared to OPC as control specimen. nanometakaolin and nanometaclay inclusion in cement paste will be evaluated for morphology effect by using Scanning Electron Microscope (SEM), chemical composition by using X-Ray Fluorescent (XRF) technique and strength properties. From morphology evaluation, the shape of the particles and particularisation of the matrix observed on the nanometakaolin, nanometaclay and plain cement paste were compared. Similarly, the strength of the plain cement paste shows was compared with those of nanometakaolin and nanometaclay. From the results, shows that inclusion of nanometakaolin at 7% additives generates early strength of cement paste and at 28 days of age addition of 1% of nanometakaolin was found to be the optimum addition level. The addition of 1% nanometakaolin acts as an ultra-filler and refines the microstructure of concrete. Furthermore, nanometakaolin also produces a secondary hydration product by optimizing the remaining calcium hydroxide which was not fully removed during the hydration period.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

19-24

Citation:

Online since:

January 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Sobolev K., F.I., Hermosillo R., Torres-Martinez L.M. , Nanomaterials and Nanotechnology for High-Composites. SP-254—8. Nanotechnology of Concrete: Recent Developments and Future Perspectives. ACI. K. Sobolev and S.P. Shah p.93 – 120, (2008).

DOI: 10.14359/20213

Google Scholar

[2] Sobolev, K., The development of a new method for the proportioning of high-performance concrete mixtures. Cement and Concrete Composites, 2004. 26(7): pp.901-907.

DOI: 10.1016/j.cemconcomp.2003.09.002

Google Scholar

[3] Tobón, J.I., et al., Mineralogical evolution of Portland cement blended with silica nanoparticles and its effect on mechanical strength. Construction and Building Materials, 2012. 36(0): pp.736-742.

DOI: 10.1016/j.conbuildmat.2012.06.043

Google Scholar

[4] Aly, M., et al., Effect of colloidal nano-silica on the mechanical and physical behaviour of waste-glass cement mortar. Materials & Design, 2012. 33(0): pp.127-135.

DOI: 10.1016/j.matdes.2011.07.008

Google Scholar

[5] Hamed Nabizadeh Rafsanjani, M.K., Application of Nanotechnology in Civil Engineering. Advanced Materials Research, Vols. 261 – 263, p.520 – 523, (2011).

DOI: 10.4028/www.scientific.net/amr.261-263.520

Google Scholar

[6] Ali Nazari, S.R., Improvement compressive strength of concrete in different curing media by Al2 O3 nanoparticles. Materials Science and Engineering A, Vol. 528, p.1183 – 1191, (2010).

DOI: 10.1016/j.msea.2010.09.098

Google Scholar

[7] Steins, P., et al., Structural evolution during geopolymerization from an early age to consolidated material. Langmuir, 2012. 28(22): pp.8502-8510.

DOI: 10.1021/la300868v

Google Scholar

[8] Riahi, A.N. a.S., The effect of Ti O2 nanoparticles on water permeability and thermal and mechanical of high strength self-compacting concrete. Materials Science and Engineering A, Vol. 528, p.756 – 763, (2010).

DOI: 10.1016/j.msea.2010.09.074

Google Scholar

[9] A.A. Ramezanianpour, H.B.J., Influence of metakaolin as supplementary cementing material on strength and durability of concretes. Construction and Building Materials 30 (2012) 470–479, (2012).

DOI: 10.1016/j.conbuildmat.2011.12.050

Google Scholar

[10] Assem A.A. Hassan, M.L., Khandaker M.A. Hossain, Effect of metakaolin and silica fume on the durability of self-consolidating concrete. Cement & Concrete Composites, (2012).

DOI: 10.1016/j.cemconcomp.2012.02.013

Google Scholar

[11] Babanajad, S.K., Y. Farnam, and M. Shekarchi, Failure criteria and triaxial behaviour of HPFRC containing high reactivity metakaolin and silica fume. Construction and Building Materials, 2012. 29(0): pp.215-229.

DOI: 10.1016/j.conbuildmat.2011.08.094

Google Scholar

[12] A. M, N., Properties of Concrete2005: Fourth Edition, Prentice Hall.

Google Scholar