Photochemical Synthesis of Pd Core @ Pt Shell Nanoparticles in Polyethylene Glycol (PEG) Solution System

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In the sodium citrate solution systems containing double metal ions with different Pd-Pt molar ratios and single Pt (IV) ions, Pd Core @ Pt Shell nanoparticles were synthesized by the photochemical coreduction and Pd seed method, respectively. By means of characterization of TEM, the change regularity of the composite nanoparticle sizes was studied in both preparation methods. The surface chemical state of the composite nanoparticles and their structure were analyzed by X-ray photoelectron spectroscopy (XPS), confirming that Pd @ Pt nanoparticles formed are core-shell structure. Keywords: Pd Core @ Pt Shell; Photochemical; Simultaneous reduction; Seeding growth

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753-757

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February 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Hong Wang, Changwei Xu, Faliang Cheng, et al. Pd/Pt core–shell nanowire arrays as highly effective electrocatalysts for methanol electrooxidation in direct methanol fuel cells [J]. Electrochemistry Communications, 2008, 10: 1575–1578.

DOI: 10.1016/j.elecom.2008.08.011

Google Scholar

[2] Yuan Wang, Naoki Toshima. Preparation of Pd-Pt Bimetallic Colloids with Controllable Core/Shell Structures [J]. J. Phys. Chem. B, 1997, 101: 5301-5306.

DOI: 10.1021/jp9704224

Google Scholar

[3] Sergio I. Sanchez, Matthew W. Small, Jian-min Zuo, et al. Structural Characterization of Pt-Pd and Pd-Pt Core-Shell Nanoclusters at Atomic Resolution [J]. J. Am. Chem. Soc., 2009, 131: 8683–8689.

DOI: 10.1021/ja9020952

Google Scholar

[4] Dong Shouan, Tang Chun. Photochemical Synthesis of Colloidal Gold Particles by the Sunlight Radiation using a Seeding Approach [J]. Gold Bulletin, 2004, 37(3-4): 187-195.

DOI: 10.1007/bf03215212

Google Scholar

[5] Dong Yingnan, Dong Shouan, Tang Chun. Photochemical Synthesis and Characterization of Gold@Palladium Core-Shell Composite Nanoparticles [J]. Chem J Chinese U., 2009, 30(7): 1397-1401.

Google Scholar

[6] Dong Yingnan, Dong Shouan, Tang Chun, Yang Xikun. Photochemical Synthesis and Electro-catalytic Activity of Au Core/Pt Shell Composite Nanoparticles [J]. Rare Metal Mat Eng., 2013, 42(4): 789-792.

DOI: 10.1016/s1875-5372(15)60047-9

Google Scholar

[7] Li Shanshan, Dong Yingnan, Bi Xiaoguo, Tang Meiling. Synthesis of Au@Pt Core-Shell Nanoparticles with High Electro-catalytic Activity of Methanol Oxidation by Photochemical Seeding Growth [J]. Int. J. Electrochem. Sci., 2013, 8: 8662-8668.

DOI: 10.1016/s1875-5372(15)60047-9

Google Scholar

[8] Yingnan Dong, Shouan Dong, Zaifu Pan, et al. Synthesis of Ag Core @ Au Shell Composite Nanoparticles by Spontaneous Deposit Au on the Surface of Ag Seeds [J]. AMM., 110-116: 1030-1035.

DOI: 10.4028/www.scientific.net/amm.110-116.1030

Google Scholar

[9] Xu Jiaozhen, Yang Ping, Hua Nanping, et al. Preparation and characterization of bimetallic Pt/Au nanoparticles [J]. Chem Res Appl., 2003, 15(6): 838-840.

Google Scholar

[10] Moulder J F. Handbook of X-Ray Photoelectron Spectroscopy [M]. Eden Prairie: Perkin-Elmer Physical Electronics DiVision, 1992: 234.

Google Scholar