Solid State Chemical Reaction Synthesis and Characterization of Nanocrystalline Cerium Carbonate Rare Earth Compound

Abstract:

Under the conditions of the presence of surfactants and ultrasonication, the use of different cerium salt, respectively, with carbonate under solid state chemistry reactions, the synthesis of nanorare earth metal complexes of cerium carbonate crystals was formed. The solid phase was characterized by powder X-ray diffraction (XRD) and electron diffraction (ED). The particle size, its distribution, and morphology of the prepared nanocrystallite were observed by transmission electron microscopy (TEM). The results show that particle sizes are relatively uniform, the morphology of the crystal is spherical, the average particle diameter is about 60 nm, and the yield rate is approximately 93.2%. Furthermore, during the synthesis, the solid-state reaction conditions including raw materials, matching proportion of reactants, additions of inert substance, addition of trace solvents, surfactants and porphyrization time, etc, all have some influence on the morphology, particle size and size distribution of the final products. During the synthesis of the cerium carbonate nanocrystallites, the solid state reaction conditions such as changing reactant, matching proportion of reactant, adding inert substance, joining a little solvent or surface active solvent and grinding at different times may influence morphology, particle size and the size distribution of final products.

• Periodical: Applied Mechanics and Materials (Volumes 543-547)
• Pages: 3776-3780
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.543-547.3776
• Online since: March 2014
• Authors: Dao Hua Li*, Shao Fen He
• Keywords: Cerium Carbonate, Characterization, Nanocrystallite, Rare Earth Compound, Solid-State Synthesis, Ultrasonication

References

[1] Zhuang Jia, Chi Yanhua, Wang Dong. Preparation of Different Topography NiCo2O4 with Surfactant by Solid State Reaction[J] Journal of Inorganic Materials, 2007, 22(1): 40.

[2] Wang Y. Nano and Submicron-structured Sulfide Self-lubricating Coatings[J]. Tribology Letters, 2004, 17(2): 165.

DOI: 10.1023/b:tril.0000032441.09602.40

[3] Tong W P, Tao N R, Wang Z B, et al. Nitriding Iron at Lower Temperatures[J]. Science, 2003, 299: 686.

[4] Kim Y. C, Kim W T, Kim D. H. A Development of Ti-based Bulk Metallic Glass[J]. Mater. Sci. Eng. A, 2004, 375-377: 127.

DOI: 10.1016/j.msea.2003.10.115

[5] Guo F Q, Wang H J, Poon S J, et al. Ductile Titanium-based Glassy Alloy Ingots[J]. Appl. Phys. Lett., 2005, 86.

DOI: 10.1063/1.1872214

[6] Wang Hong; Zhu Lunyu; Chen Mingcai. Effects of La2O3/Li2O/TiO2-Coating on Electrochemical Performance of LiCoO2 Cathode[J]. Journal of Rare Earths, 2007, 25(1): 124.

DOI: 10.1016/s1002-0721(07)60058-1