Research on the Regularity and Mechanism of Copper Corrosion in Air Containing Sulfur Dioxide

Abstract:

Copper corrosion in air containing sulfur dioxide atmosphere was described in detail, for which was one of the most primary atmospheric corrosion.In the first, effection from the synergy of pure sulfur dioxide gas and mixed gas on copper corrosion was set out, together with the introduction of certain corrosion products and formation mechanism. Besides, initial copper corrosion behaviors in variety gas concentration as well as different film thickness were summarized using electrochemical method. The research prospects were depicted in the last.

• Periodical: Applied Mechanics and Materials (Volumes 543-547)
• Pages: 3853-3856
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.543-547.3853
• Online since: March 2014
• Authors: Han Tao Ren*, Sen Liu, Ping Wang, Song Xu, Hui Bo Zhou
• Keywords: Atmospheric Corrosion, Copper, Sulfur Dioxide

References

[1] B. De Filippo, L. Campanella, A. Brotzu, et al. Characterization of bronze corrosion products on exposition to sulphur dioxide[J]. Advanced Materials Research, 2010, 138(21): 21-28.

DOI: 10.4028/www.scientific.net/amr.138.21

[2] G. Giovannelli, S. Natali, L. Zortea, et al. An investigation into the surface layers formed on oxidised copper exposed to SO2 in humid air under hypoxic conditions. Corrosion Science, 2012, 57(8): 104-113.

DOI: 10.1016/j.corsci.2011.12.028

[3] Güray Kilinççeker, Nursen Taze, Hasan Galip, et al. The effect of sulfur dioxide on iron, copper and brass[J]. Anti-Corrosion Methods and Materials, 2011, 58(1): 4-12.

DOI: 10.1108/00035591111097648

[4] Chuanwei Yan, Yufan He, Haichao Lin, et al. Initial regularity and mechanism of copper corrosion in air containing SO2[J]. The Chinese Journal of Nonferrous Metals, 2000, 10(5): 645-647.

[5] ERIKSSON P, JOHANSSON L-G, STRANDBERG H. Initial stages of copper corrosion in humid air containing SO2 and NO2[J]. Journal of Electrochemical Society, 1993, 140: 53-59.

DOI: 10.1149/1.2056109

[6] Jun Wu, Xianliang Zhou, Chaofang Dong, et al. The research progress of copper and copper alloy in atmospheric corrosion[J]. Corrosion Science And Protection Technology, 2010, 22(5): 464-465.

[7] TIDBLAD J, LEYGRAF C. Atmospheric corrosion effects of SO2 and NO2 a comparison of laboratory and field-exposed copper[J]. Journal of the Electrochemical Society, 1995, 142(3): 749-756.

DOI: 10.1149/1.2048529

[8] Jong-Sang Youn, Zhen Wang, Anna Wonaschutz, et al. Evidence of aqueous secondary organic aerosol formation from biogenic emissions in the North American Sonoran Desert [J]. Geophysi-cal Research Letters, 2013, 40(13): 3468-3472.

DOI: 10.1002/grl.50644

[9] WATANABE Masamitsu, HIGASHI Yasuhiro, Tohru Tanaka. Differences between corrosion products formed on copper exposed in Tokyo in summer and winter[J]. Corrosion Science, 2003, 45: 1439-1453.

DOI: 10.1016/s0010-938x(02)00245-7

[10] Cora C. Wohlgemuth-Ueberwasser. Sulfide oxidation as a process for the formation of copper -rich magmatic sulfides [J]. Miner Deposita, 2013, 48(7): 115-127.

DOI: 10.1007/s00126-012-0420-9

[11] STRANDBERG H. Reaction of copper patina compounds: ⅡInfluence of sodium chloride in the presence of some air pollutants[J]. Atmospheric Environment, 1998, 32(20): 3521-3526.

DOI: 10.1016/s1352-2310(98)00058-2

[12] LEYGRAF C, GRAEDEL T E. Atmospheric Corrosion[M]. New York: John Wiley& Sons, Inc., (2000).

[13] KRÄTSCHMER A, ODNEVALL WALLINDER I, LEYGRAF C. The evolution of outdoor copper patina[J]. Corrosion Science, 2002, 44: 425-450.

DOI: 10.1016/s0010-938x(01)00081-6

[14] JOUEN S, JEAN M, HANNOYER B. Simultaneous copper runoff and copper surface analysis in an outdoor area[J]. Surface and Interface Analysis, 2000, 30: 145-148.

DOI: 10.1002/1096-9918(200008)30:1<145::aid-sia825>3.0.co;2-c

[15] Shaodong Sun, Yuexia Sun, Xiaozhe Zhang, et al. A surfactant-free strategy for controllable growth of hierarchical copper oxide nanostructures[J]. CystEngComm, 2013(26): 62-65.

DOI: 10.1039/c3ce40522b

[16] Arne H. Zittlau, Quan Shi, Juliana Boerio-Goates, et al. Thermodynamics of the basic copper sulfates antlerite, posnjakite, and brochantite[J]. Chemie der Erde-Geochemistry, 2013, 73(1): 39-50.

DOI: 10.1016/j.chemer.2012.12.002

[17] Honghua Ge, Fei Song, Ruifeng Guo et al. Study of the corrosion of copper in air containing sulfur dioxide[J]. Journal of Shanghai University of Electric Power, 2010, 26(6): 577-580.