Effects of Temperature and Volume Agglomerate Fraction on Mechanical Response of PEMFC Electrodes

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To deal with the durability analysis of PEM fuel cell, it is necessary to carry out a further understanding of each component response, especially each layer of the MEA. So the main purpose of this paper is to understand the mechanical properties of electrode layer and find out the effect of temperature and the content of catalyst particles on the electrode yield stress. To overcome the experimental limitations, numerical method is used here. A 3-phase model of the electrode is built, which includes a user-defined material with catalyst particles. Due to the porosity of the electrode, the user-defined material is defined as a nafion ionomer glassy constitutive model by bringing in the effect of foam structure. Catalyst agglomerate particles are assumed as isotropic elastic spheres with relatively high Young’s modulus. The yield stress is extracted from the simulation, and the influences of temperature and agglomerate fraction on it are discussed.

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379-382

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April 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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