Biofuels Produced from Hydrothermal Liquefaction of Rice Husk

Article Preview

Abstract:

This research is conducted for getting and examining bio-fuel from the process of hydrothermal liquefaction (HTL) using rice husk as raw material. The HTL process used ethanol as a solvent with concentration of 96%. Properties of the produced light fuels were examined on parameter such as water content, viscosity, calorific value, density, flash point, and gas chromatography-mass spectroscopy (GC-MS). The optimum yield 36.3 wt% of light fuel from HTL process of rice husk occurred at reactor temperature of 325°C and holding time of 45 minutes. Meanwhile, the optimum production of bio-fuel (light fuel + heavy fuel) was 69.3 wt% at reactor temperature of 325 °C and holding time of 30 minutes. The resulted light fuel has the calorivic value from 12.1 to 20.2 MJ/kg, viscosity from 1.11 to 1.6 cSt, and flash point from 14 to 29 °C. For the yield of bio-fuel from HTL process, the effect of reactor temperature was more pronounced than the effect of holding time. Further, the light fuels from HTL process with low water content are interesting objects as a fuel in internal combustion engines.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

628-634

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. Boerrigter and , H.D. Uil, Green diesel from biomass via fischer-tropsch synthesis: New insights in gas cleaning and process design, Strasbourg, France (2002).

Google Scholar

[2] F.E.M. Farias and , F.R.C. Silva, Effect of operating conditions on fischer-tropsch liquid products, Latin American Applied Research. 37 (2007), pp.283-287.

Google Scholar

[3] J. Akhtar and , N.A.S. Amin, A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass, Renew. Sust. Energy Rev. 15 (2011), pp.1615-1624.

DOI: 10.1016/j.rser.2010.11.054

Google Scholar

[4] P. Biller, A.B. Ross, Potential yields and properties of oil from hydrothermal liquefaction of microalgae with different biochemical content, Bioresour. Technol. 102 (2011), pp.215-225.

DOI: 10.1016/j.biortech.2010.06.028

Google Scholar

[5] J. Gan and , W. Yuan, Operating condition optimization of corncob hydrothermal conversion for bio-oil production, Bioresour. Technol. 107 (2012), p.350–357.

DOI: 10.1016/j.apenergy.2012.09.053

Google Scholar

[6] Z. Liu and , F. -S. Zhang, Effects of various solvents on the liquefaction of biomass to produce fuels and chemical feedstocks, Energy Conversion and Management. 49 (2008), p.3498–3504.

DOI: 10.1016/j.enconman.2008.08.009

Google Scholar

[7] S. Yin and , Z. Tan, Hydrothermal liquefaction of cellulose to bio-oil under acidic, neutral and alkaline conditions, Appl. Energy. 92 (2012), pp.234-239.

DOI: 10.1016/j.apenergy.2011.10.041

Google Scholar

[8] R. Zanzi, K. Sjostrom and , E. Bjornbom, Rapid pyrolysis of bagasse at high temperature, 3rd Asia-Pacific International Symposium on Combustion and Energy Utilization. Hong Kong (1995).

Google Scholar

[9] R. Zanzi, K. Sjostrom and , E. Bjornbom, Rapid high-temperature pyrolysis of biomass in a free-fall reactor, Fuel. 75 (1996), pp.545-550.

DOI: 10.1016/0016-2361(95)00304-5

Google Scholar

[10] M. Taisuke and , M. Kouichi, A simulation model for the pyrolysis of orimulsion, Energy Fuels. 11 (1997), pp.819-824.

Google Scholar

[11] A.V. Bridgwater and , G.V.C. Peacocke, Fast pyrolysis processes for biomass, Renew. Sust. Energy Rev. 4 (2000), pp.1-73.

Google Scholar

[12] Suyitno, F. Lettner, CFD modelling of external heated pyrolysis of wood chips, 14th European Biomass Conference. Paris, France (2005).

Google Scholar

[13] Suyitno, F. Lettner, H. Timmerer and , P. Haselbacher, Devolatilization in biomass pyrolysis: Influence of solid size, moisture content and heat radiation, International Energy Conference. Jakarta, Indonesia (2005).

Google Scholar

[14] Z.J. Lu, Bio-oil from fast pyrolysis of rice husk: Yields and related properties and improvement of the pyrolysis system, J. Anal. Appl. Pyrolysis. 80 (2007), pp.30-35.

DOI: 10.1016/j.jaap.2006.12.030

Google Scholar

[15] C. Xu and , T. Etcheverry, Hydro-liquefaction of woody biomass in sub- and super-critical ethanol with iron-based catalysts, Fuel. 87 (2008), pp.335-345.

DOI: 10.1016/j.fuel.2007.05.013

Google Scholar

[16] A. Brems, R. Dewil, J. Baeyens, J.P.K. Seville, C. Prayogo and , G. Bending, The future of biomass pyrolysis in the production of value-added products, Proceedings of the SDEWES Conference. (2011) 26-29.

Google Scholar

[17] S. Xiu and , A. Shahbazi, Bio-oil production and upgrading research: A review, Renewable and Sustainable Energy Reviews. 16 (2012), pp.4406-4414.

DOI: 10.1016/j.rser.2012.04.028

Google Scholar

[18] A. Bridgwater, Biomass fast pyrolysis, Thermal Science. 8 (2004), pp.21-49.

Google Scholar

[19] L. Fagbemi, L. Khezami and , R. Capart, Pyrolysis products from different biomasses: Application to the thermal cracking of tar, Applied Energy. 69 (2001), pp.293-306.

DOI: 10.1016/s0306-2619(01)00013-7

Google Scholar

[20] F. Karaosmonaglu, E. Tetik and , E. Göllü, Biofuel production using slow pyrolysis of the straw and stalk of the rapessed plant, Fuel Processing Technology. 59 (1999), pp.1-12.

DOI: 10.1016/s0378-3820(99)00004-1

Google Scholar

[21] C. Wang, Z. Du, J. Pan, J. Li, Z. Yang, Direct conversion of biomass to bio-petroleum at low temperature, Pyrolysis. 78 (2007) 438-444.

DOI: 10.1016/j.jaap.2006.10.016

Google Scholar

[22] J. Li, L. Wu, Z. Yang, Analysis and upgrading of bio-petroleum from biomass by direct deoxy-liquefaction, J. Anal. Appl. Pyrolysis. 81 (2008) 199-204.

DOI: 10.1016/j.jaap.2007.11.004

Google Scholar

[23] C.S. Theegala, J.S. Midgett, Hydrothermal liquefaction of separated dairy manure for production of bio-oils with simultaneous waste treatment, Bioresour. Technol. 107 (2012) 456–463.

DOI: 10.1016/j.biortech.2011.12.061

Google Scholar

[24] Z. Shuping, W. Yulong, Y. Mingde, I. Kaleem, L. Chun, J. Tong, Production and characterization of bio-oil from hydrothermal liquefaction of microalgae dunaliella tertiolecta cake, Energy. 35 (2010) 5406-5411.

DOI: 10.1016/j.energy.2010.07.013

Google Scholar

[25] B.R. Moser, Biodiesel production, properties, and feedstocks, 45 (2009) 229–266.

Google Scholar

[26] G. Knothe, K.R. Steidley, Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components, Fuel. 84 (2005) 1059–1065.

DOI: 10.1016/j.fuel.2005.01.016

Google Scholar

[27] J.P. Diebold, A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils, NREL, 1022, (2000).

Google Scholar