Biofilm Green Packaging: Characterization and Biodegradation Studies

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Low Density Polyethylene was blended with various contents of tapioca starch (10%, 20%, 30%, and 40%) with addition of compatibilizer, i.e. PE-g-MA and cooking oil as plasticizer. The blends were prepared by co-rotating twin screw extrusion process and characterized by melt flow index (MFI) analysis and tensile test. Tapioca starch based polyethylene biofilms were studied in term of biodegradability by fungi test. The increasing starch content to LDPE blend reduced the MFI values and tensile strength but in 30% and 40% of starch content in tensile strength is higher than control LDPE’s strength due to molecular orientation in sample. However, incorporation of PE-g-MA as compatibilizer increases the mechanical properties of starch based polyethylene blends due to the reaction between maleated PE and starch, thus improves adhesion and reduces slippage at matrix-filler interface. The increasing of TS also increase the water content in film sample, weight loss percentage in TGA, and percentage degradation of LDPE/TS blend film.

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67-71

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August 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Cerclé, C., P. Sarazin, and B. C. Daviz, High Performance Polyethylene/Thermoplastic Starch Blends Through Controlled Emulsification Phenomena., Carbohydrate Polymers, 92, pp.138-148, (2013).

DOI: 10.1016/j.carbpol.2012.08.107

Google Scholar

[2] Willett, J. L, Mechanical Properties of LDPE/Granular Starch Composites., Journal of Applied Polymer Science, 54, pp.1685-1695, (1994).

DOI: 10.1002/app.1994.070541112

Google Scholar

[3] Liu, H., F. Xie, L. Yu, L. Chen, and L. Li, Thermal Processing of Starch-based Polymers., Progress in Polymer Science, 34, pp.1348-1368, (2009).

DOI: 10.1016/j.progpolymsci.2009.07.001

Google Scholar

[4] Raj, B., U. Sankar, and Siddaramaiah, Low Density Polyethylene/Starch Blend Films for Food Packaging Applications., Advances in Polymer technology, 23, pp.32-45, (2004).

DOI: 10.1002/adv.10068

Google Scholar

[5] Lawton, J. W., Effect of Starch Type on the Properties of Starch Containing Films., Carbohydrate Polymers, 29, pp.203-208, (1996).

DOI: 10.1016/0144-8617(96)00028-8

Google Scholar

[6] Matzinos, P., V. Tserki, C. Gianikouris, E. Pavlidou and C. Panayiotou, Processing and Characterization of LDPE/starch/PCL blends., European Polymer J., 38, pp.1713-1720, (2002).

DOI: 10.1016/s0014-3057(02)00061-7

Google Scholar

[7] Chandra, R. and R. Rutsgi, Biodegradation of Maleated Linear Low Density Polyethylene and Starch Blends., Polymer Degradation and Stabilization, 56, pp.185-202, (1997).

DOI: 10.1016/s0141-3910(96)00212-1

Google Scholar

[8] Shah, P.B., Bandopadhyay and J. R. Bellare, Environmentally degradable starch filled low density polyethylene, Polymer Degradation and Stability, Vol 47, pp.165-173, (1995).

DOI: 10.1016/0141-3910(94)00088-p

Google Scholar