Preparation and Coating Properties of Silicone/Cuprous Modified Acrylic Resin

Article Preview

Abstract:

The modified resins, as antibacterial coating materials, have attracted wide attention. Two steps to obtain resins: cuprous oxide collosol particle was prepared by reduction of Copper acetate solution, using hydrazine as the reducing agent, then oleic acid was added to the system as the covered agent; silicone and cuprous modified acrylic resin was successfully synthesized by solution polymerization with the monomers of acrylic acid (AA), butyl acrylate (BA), methyl methacrylate (MMA), vinyl triethoxy silane (VTES) and the as-prepared oleic acid coated Cu2O sol, using the azobisisobutyronitrile (AIBN) as the initiator. The samples were characterized by X-ray Photoelectron Spectroscopy (XPS) and FTIR analysis. The effects of silicone content on the properties of polymer coatings were investigated by contact angle analysis.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

105-108

Citation:

Online since:

August 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Li Z, Han W, Kozodaev D, Brokken-Zijp JCM, de With G, Thune PC (2006) Surface properties of poly(dimethylsiloxane)-based inorganic/organic hybrid materials. Polymer 47: 1150–1158.

DOI: 10.1016/j.polymer.2005.12.057

Google Scholar

[2] Sonnenschein MF, Webb SP, Wendt BL (2008) Poly(acrylate/siloxane) hybrid adhesives for polymers with low surface energy. Int J Adhesion Adhesives 28: 126–134.

DOI: 10.1016/j.ijadhadh.2007.07.001

Google Scholar

[3] Dong J, Liu Z, Feng Y, Zheng C (2006) Preparation, morphology, and mechanical properties of elastomers based on a, w-dihydroxy-polydimethylsiloxane/poly(methyl methacrylate) blends. J Appl Polym Sci 100: 1547–1553.

DOI: 10.1002/app.23350

Google Scholar

[4] Nakajima A, Abe K, Hashimoto K, Watanabe T (2000) Preparation of hard super-hydrophobic films with visible light transmission. Thin Solid Films 376: 140–143.

DOI: 10.1016/s0040-6090(00)01417-6

Google Scholar

[5] K. Shimamura, Y. Matsumoto, T. Matsunaga, Surf. Coat. Technol. 50 (1992) 127.

Google Scholar

[6] J. Kim, M. Cho, B. Oh, S. Choi, J. Yoon, Chemosphere 55 (2004) 775.

Google Scholar

[7] Yu Z, Zhang Z, Yuan Q, Ying S (2002) Surface analysis of coating based on novel water-diluted fluorinated polymer/silica hybrids. Adv Polym Technol 21: 268–274.

DOI: 10.1002/adv.10030

Google Scholar

[8] Castelvetro V, Ciardelli F, Francini G, Baglioni P (2000) On the surface properties of waterborne fluorinated coating polymers. Macromol Mater Eng 278: 6–16.

DOI: 10.1002/(sici)1439-2054(20000501)278:1<6::aid-mame6>3.0.co;2-8

Google Scholar

[9] Zhu Q, Han CC (2007) Synthesis and crystallization behaviors of highly fluorinated aromatic polyesters. Polymer 48: 3624–3631.

DOI: 10.1016/j.polymer.2007.04.035

Google Scholar

[10] Smith SD, Desimone JM, Huang H, York G, Dweight DW, Wikes GL, McGrath JE (1992) Synthesis and characterization of poly(methyl methacrylate)-g-poly(dimethylsiloxane)copolymers. I. Bulk and surface characterization. Macromolecules 25: 2575–2581.

DOI: 10.1021/ma00036a002

Google Scholar