Structure Studies on Order Assemblage of Manganese II Isovanillin Complexes

Yu Liu; Shan Shan Zhang; Da Jun Song; Tian Zhu Yang; Hong Xiao Tian; Jian Gao

doi:10.4028/www.scientific.net/AMM.618.193

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 618Structure Studies on Order Assemblage of Manganese...

Structure Studies on Order Assemblage of Manganese^II Isovanillin Complexes

Abstract:

The Manganese^II Isovanillin complex [Mn₂(C₈H₇O₃)₄(H₂O)₂], Diaqua-tetra (isovanillinato-O,O')-bis (manganese^II),the Mn^II atom is coordinated by three isovanillinate anions and one water molecule in a distorted trigonal bipyramidal configuration with five-coordinations geometry. And one isovanillinate ligand chelates to the Mn^II atom through its methyl and hydroxy O atoms, the other two isovanillinate ligand chelates to the Mn^II atom only through its hydroxy O atoms. The same as another Mn^II atom. So we get a Binuclear Mn^II metal complexe. The fact clearly suggests not so much significant contribution from the electrostatic interaction in the Mn-O bonding in Binuclear Mn^II metal complexes as we gotten in mononuclear Mn^II metal complexes. Adjacent complex link to each other via hydrogen bonds forming the three-dimensional supramolecular structure.

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Periodical:

Applied Mechanics and Materials (Volume 618)

Pages:

193-197

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.618.193

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Online since:

August 2014

Authors:

Yu Liu*, Shan Shan Zhang, Da Jun Song, Tian Zhu Yang, Hong Xiao Tian, Jian Gao

Keywords:

Binuclear, Electrostatic Interaction, Manganese^IIIsovanillin Complex, Photosystem Ii, Supramolecular Structure

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