Pyrolytic Synthesis of Bifunctional g-C3N4 Derived from Melamine

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Graphitic carbon nitride (g-C3N4) polymer material was synthesized via a simple approach by directly heating melamine as the precursor at 500°C. The phase composition, chemical functional groups, and surface morphology of the obtained product were studied by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM), respectively. All the characterization results identified the formation of g-C3N4 with stack-layered structure. The absorption and photocatalytic performance of as-synthesized g-C3N4 for the discoloration of an active dye, Methylene Blue (MB), were proved to be excellent and control experiments inferred that adsorption and photocatalysis governed the MB discoloration under UV irradiation. The repeated experiments indicated that the obtained sample could be reused more than five times without loss of its absorption capacity and photocatalytic activity.

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215-219

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August 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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