Preparation and Photocatalytic Activity of Gold Nanoparticles (AuNPs)/ZnFe2O4

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Gold nanoparticles (AuNPs)/ZnFe2O4 nanocomposites were prepared by a colloidal deposition (CD) method. The as-prepared AuNPs/ZnFe2O4 nanocomposites were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with energy dispersive spectrum (EDS). XRD results showed that the diffraction peaks of AuNPs gradually increased with the increase of AuNPs content. SEM observations revealed that the AuNPs were presented as regular nanoparticles on the ZnFe2O4 in all the composites. With the increase in Au content, the amount of AuNPs deposited on ZnFe2O4 surface increased. EDS element analysis indicated that the actual content of AuNPs in nanocomposites was consistent with its preset value before preparation by CD method. An active dye, Methyl Orange (MO), was employed as the target pollutant to evaluate the photocatalytic activity of AuNPs/ZnFe2O4 under UV irradiation. The photocatalytic evaluation showed that MO discoloration ratio could reach 72.17% when the nanocomposite with AuNPs content of 5 wt.% was used as the photocatalyst. Finally, the possible mechanism for the enhanced photocatalytic activity of ZnFe2O4 by AuNPs was proposed.

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198-202

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August 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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