Study on the Recovery of 1-butyl-3-methylimidazolium-based Ionic Liquids

Article Preview

Abstract:

Nowadays, ionic liquids have been widely used in desulfurization process. However, the synthesis costs, performance efficiencies and problems related to waste waters contaminated with ionic liquids are the major issues that need to be considered. Thus, recovery method is one of the alternatives to overcome the current issues. 1-butyl-3-methylimidazolium-based ionic liquids with three different anions: dicyanamide (N(CN)2), thiocyanate (SCN) and methylsulfate (CH3SO4) were chosen for the study because they are the common ionic liquids used in desulfurization. The recovery process used is water washing which is the cheapest and easiest recovery method. Even though the contaminants in the spent ionic liquids can easily be removed, we found that the recovered ionic liquids contained higher percentage of water as compared to the pure and spent ionic liquids. Thus, the aim of this current work is to study on the feasibility of the spent ionic liquids to be recovered and their performance on desulfurization after being recovered.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

144-147

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] E. M. Siedlecka, M. Czerwicka, J. Neumann, P. Stepnowski, J. F. Fernández, and J. Thöming, Ionic Liquids: Methods of Degradation and Recovery, in Ionic Liquids: Theory, Properties, New Approaches, A. Kokorin, Ed., ed: InTech, 2011, p.738.

DOI: 10.5772/15463

Google Scholar

[2] A. Bosmann, L. Datsevich, A. Jess, A. Lauter, C. Schmitz, and P. Wasserscheid, Deep desulfurization of diesel fuel by extraction with ionic liquids, Chem Commun (Camb), pp.2494-5, Dec 7 (2001).

DOI: 10.1039/b108411a

Google Scholar

[3] C. D. Wilfred, C. F. Kiat, Z. Man, M. A. Bustam, M. I. M. Mutalib, and C. Z. Phak, Extraction of dibenzothiophene from dodecane using ionic liquids, Fuel Processing Technology, vol. 93, pp.85-89, Jan (2012).

DOI: 10.1016/j.fuproc.2011.09.018

Google Scholar

[4] M. B. T. John D. Holbrey, Robin D. Rogers, Selection of Ionic Liquids for Green Chemical Applications, American Chemical Society, pp.2-11, (2003).

Google Scholar

[5] M. Nefedieva, O. Lebedeva, D. Kultin, L. Kustov, S. Borisenkova, and V. Krasovskiy, Ionic liquids based on imidazolium tetrafluoroborate for the removal of aromatic sulfur-containing compounds from hydrocarbon mixtures, Green Chemistry, vol. 12, pp.346-349, (2010).

DOI: 10.1039/b916789g

Google Scholar

[6] R. Chang, Chemistry, 8th ed. New York: McGraw-Hill, (2005).

Google Scholar