Preparation and Characterization of Rice Husk Ash for Adsorption of Phenol from Aqueous Solutions

Article Preview

Abstract:

In this research, the development of three (3) low-cost adsorbent materials from abundant waste rice husk was achieved via thermal treatment. The physiochemical properties of the developed adsorbents were evaluated. Their adsorption behaviours in batch system were evaluated for the removal of phenol from aqueous solutions by varying the pH (2 to 10). It was found that, the rice husk ash burned a 400oC for 1hr ‘RHA400,1’ has the highest surface area (201.36 m2.g-1) followed by RHA300,4 (87.08 m2.g-1) and RHA600,1 (43.22 m2.g-1), respectively. RHA400,1 had shown the highest removal efficiency followed by RHA300,4 and RHA600,1, towards phenol due to high surface area and porosity. The maximum uptake of phenol was found at pH 4. The adsorption kinetics was well described by both pseudo-second order and the Elovich models.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

498-502

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] P.S. Nayak, B. K. Singh, Removal of phenol from aqueous solutions by sorption on low cost clay, Desalination. 207 (2007) 71-79.

DOI: 10.1016/j.desal.2006.07.005

Google Scholar

[2] G. Busca, S. Berardinelli, C. Resini, L. Arrighib, Technologies for the removal of phenol from fluid streams: A short review of recent developments, J. Hazard. Mater. 160 (2008) 265–288.

DOI: 10.1016/j.jhazmat.2008.03.045

Google Scholar

[3] M. Ahmaruzzaman, D.K. Sharma, Adsorption of phenols from wastewater, J. Colloid Interface Sci. 287 (2005) 14-24.

DOI: 10.1016/j.jcis.2005.01.075

Google Scholar

[4] Z. Aksu, Application of biosorption for the removal of organic pollutants: a review, Process Biochemistry. 40 (2005) 997-1026.

DOI: 10.1016/j.procbio.2004.04.008

Google Scholar

[5] S. Altenor, B. Carene, E. Emmanuel, J. Lambert, J-J. Ehrhardt, S. Gaspard, Adsorption studies of methylene blue and phenol onto vetiver roots activated carbon prepared by chemical activation, J. Hazard. Mater. 165 (2009), 1029–1039.

DOI: 10.1016/j.jhazmat.2008.10.133

Google Scholar

[6] H. Cherifi, S. Haninia, F. Bentahar, Adsorption of phenol from wastewater using vegetal cords as a new adsorbent, Desalination. 244 (2009) 177-187.

DOI: 10.1016/j.desal.2008.05.022

Google Scholar

[7] A.H. Mahvi., A. Maleki, A. Eslami, Potential of rice husk and rice husk ash for phenol removal in Aqueous System, American J. Appl. Sci. 1 (4): (2004) 321-326.

DOI: 10.3844/ajassp.2004.321.326

Google Scholar

[8] B.S. Ndazi , S. Karlsson, J.V. Tesha, C.W. Nyahumwa , Chemical and physical modifications of rice husks for use as composite panels, Composites: Part A: Applied Sci. and Manufacturing. 38 (2007) 925–935.

DOI: 10.1016/j.compositesa.2006.07.004

Google Scholar

[9] D. G. Nair, K. S. Jagadish, A. Fraaij, Reactive pozzolanas from rice husk ash: An alternative to cement for rural housing, Cement and Concrete Research. 36 (2006) 1062-1071.

DOI: 10.1016/j.cemconres.2006.03.012

Google Scholar

[10] S. B. Daffalla, H. Mukhtar, M. S. Shaharun, Removal of Phenol from Aqueous Solutions using Rice Husk Ash, Caspian J. of Applied Sci. Res. (2013) 36-49.

DOI: 10.4028/www.scientific.net/amm.625.498

Google Scholar

[11] S. B. Daffalla, H. Mukhtar, M. S. Shaharun, Batch Studies of Adsorption of Phenol From Aqueous Solutions Using Rice Husk Ash, International Conference on Civil, Offshore and Environ. Eng. (ICCOEE2012), Malaysia, Kuala Lumpur (2012).

DOI: 10.4028/www.scientific.net/amm.625.498

Google Scholar

[12] L. Ren, J. Zhang, Y. Li, C., Zhang, Preparation and evaluation of cattail fiber-based activated carbon for 2, 4-dichlorophenol and 2, 4, 6-trichlorophenol removal, Chem. Eng. Journal. 168 (2011) 553-561.

DOI: 10.1016/j.cej.2011.01.021

Google Scholar

[13] Y.S. Ho, G. Mckay, Comparative sorption kinetic studies of dye and aromatic compounds onto fly ash, J. Environmental. Sci. and Health. A34 (5) (1999) 1179-1204.

DOI: 10.1080/10934529909376889

Google Scholar