Separation of Naphthenic Acid Using Hydroxide Based Ionic Liquids

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Abstract:

Isolation of naphthenic acid from model oil using hydroxide based ionic liquid was investigated. A detailed de-acidification study at different temperatures and different ionic liquid/model oil was performed and the content of naphthenic acid before and after extraction was calculated. The ILs containing hydroxide anions has the potential to completely deacidify model oil having high TAN with extremely low ionic liquid /oil ratio.

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570-573

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September 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Jing, Y. Zhong, Z. Yao, and W. Ke, Corrosion of Naphthenic acids and control, Corros. Prot. Petrochem. Ind. (Chinese), vol. 16, pp.1-7, (1999).

Google Scholar

[2] Y. Hu and G. Xue, Corrosion of equipment in processing high acid value crude and development of corrosion prevention technologies, Corrosion & Protection in Petrochemical Industry, vol. 21, pp.5-8, (2004).

Google Scholar

[3] A. S. f. Testing and Materials, ASTM D-664: Standard test method for acid number of petroleum products by potentiometric titration, Annual book of ASTM standards, (1989).

Google Scholar

[4] I. Dzidic, A. Somerville, J. Raia, and H. Hart, Determination of naphthenic acids in California crudes and refinery wastewaters by fluoride ion chemical ionization mass spectrometry, Analytical Chemistry, vol. 60, pp.1318-1323, (1988).

DOI: 10.1021/ac00164a015

Google Scholar

[5] T. P. Fan, Characterization of naphthenic acids in petroleum by fast atom bombardment mass spectrometry, Energy & Fuels, vol. 5, pp.371-375, (1991).

DOI: 10.1021/ef00027a003

Google Scholar

[6] J. Schmitter, P. Arpino, and G. Guiochon, Investigation of high-molecular-weight carboxylic acids in petroleum by different combinations of chromatography (gas and liquid) and mass spectrometry (electron impact and chemical ionization), Journal of Chromatography A, vol. 167, pp.149-158, (1978).

DOI: 10.1016/s0021-9673(00)91154-3

Google Scholar

[7] C. S. Hsu, G. Dechert, W. Robbins, and E. Fukuda, Naphthenic acids in crude oils characterized by mass spectrometry, Energy & Fuels, vol. 14, pp.217-223, (2000).

DOI: 10.1021/ef9901746

Google Scholar

[8] W. E. Rudzinski, L. Oehlers, Y. Zhang, and B. Najera, Tandem mass spectrometric characterization of commercial naphthenic acids and a Maya crude oil, Energy & Fuels, vol. 16, pp.1178-1185, (2002).

DOI: 10.1021/ef020013t

Google Scholar

[9] J. A. Brient, P. J. Wessner, and M. N. Doyle, Naphthenic acids, Kirk-Othmer Encyclopedia of Chemical Technology, (1995).

DOI: 10.1002/0471238961.1401160802180905.a01

Google Scholar