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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 665Catalytic Oxidation Removal of HCN in Tail Gas

Catalytic Oxidation Removal of HCN in Tail Gas

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Abstract:

High activity catalyst for HCN removal were prepared by immobilizing Cu2+on γ-Al2O3. The catalyst showed great activity from 150°C to 250°C. The removal efficiency of HCN were above 98%. Based on the experimental phenomena, it can be assumed that the rate controlling step of the catalytic reaction process was the generation of HNCO by HCN and O2. A prediction model consist of HCN conversion, HCN flow rate, catalyst dosage was derived by combining the Langmuir adsorption isotherm. The experimental data fitted with the prediction model very well and the model may be a worthy reference for the catalytic oxidation process of HCN.

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Periodical:

Applied Mechanics and Materials (Volume 665)

Pages:

521-527

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.665.521

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Online since:

October 2014

Authors:

Rui Jia, Ping Ning, Xue Qian Wang*, Lang Lang Wang, Yong Shi, Xiao Long Guo

Keywords:

Catalytic Oxidation, HCN, HNCO

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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