Preparation of Pd-Cu-Ce Hydrogen Separation Membrane Alloys

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Abstract:

Pd-Cu-Ce composite membrane was prepared using an electroless plating technique. The effects of temperature and pressure on permeation were studied. The resistance to sulfidation was examined by exposing alloys to simulated syngas containing a combined gas of H2 and H2S. The alloys showed sings of slight sufidation at the 0.1% H2S exposure level.

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661-664

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October 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Fernando Roa, J. Douglas Way, Preparation and characterization of Pd–Cu composite membranes for hydrogen separation, Chemical Engineering Journal, 2003, 93: 11–22.

DOI: 10.1016/s1385-8947(02)00106-7

Google Scholar

[2] Y.S. Cheng, K.L. Yeung, Palladium silver composite membranes by electroless plating technique, Journal of Membrane Science , 1999, 158: 127-141.

DOI: 10.1016/s0376-7388(99)00009-5

Google Scholar

[3] Ozlem Altinisik, Meltem Dogan, Gulsen Dogu, Preparation and characterization of palladium-plated porous glass for hydrogen enrichment, Catalysis Today, 2005, 105: 641–646.

DOI: 10.1016/j.cattod.2005.06.012

Google Scholar

[4] Jiang Boquan,Liu Xianxiang, Study on Kinetics of Palladium Inorganic Composite Membrane Prepared by Yb-La Modified Elecreoless Plating. Journal of Nanchang University, 2008, 30(1): 12-15.

Google Scholar

[5] Jianhua Tong, Caili Su, Preparation of thin Pd membrane on CeO2-modified porous metal by a combined method of electroless plating and chemical vapor deposition . Journal of Membrane Science , 2006, 269: 101–108.

DOI: 10.1016/j.memsci.2005.06.023

Google Scholar

[6] Jiang Baiquan, Yu Qiang, Research on Application of Rare Earths in Preparation of Palladium Inoganic Composite Membrane by Electroless Plating [J]. Chinese Rare Earch, 2003,24(1):20-23.

Google Scholar

[7] Rochefon A, Abon M,Delichre P et al., Alloying effect on the adsorption properties of Pd50Cu50 single crystal surface, Surf. Sci., 1993, 294(1-2):43-52.

DOI: 10.1016/0039-6028(93)90157-f

Google Scholar

[8] Conrad H, Ertl G Elatta E.Adsorption of hydrogen on palladium single crystal surfaces,Surf. Sci. , 1974, 41: 435-446.

DOI: 10.1016/0039-6028(74)90060-0

Google Scholar

[9] Jiang Baiquan, Liu Xianxiang et al., Study on Kinetics of Palladium Inorganic Composite Membrane Prepared by Yb-La Modified Electroless Plating [J]. Journal of Nanchang University, 2008, 30(1): 12-15.

Google Scholar