Thermoelectric Properties of Bulk FeSb2 and the Composite of FeSb2 and CoSb3 Prepared by Sintering

Article Preview

Abstract:

For investigating the thermoelectric properties, bulk FeSb2 and the composite of CoSb3:FeSb2=7:3 was prepared via sintering. The phases of samples were analyzed by X-ray diffraction and their thermoelectric properties were tested by electric constant instrument and laser thermal constant instrument. Experimental results show that, bulk FeSb2 and the composite of CoSb3:FeSb2=7:3 are P-type semiconductor materials. The electric resistivity of bulk FeSb2 sample increases with temperature rising while that of the composite (CoSb3:FeSb2=7:3) decreases with temperature rising. The Seebeck coefficient of the composite (CoSb3:FeSb2=7:3) is evidently higher than that of bulk FeSb2. The thermal conductivities of the composite (CoSb3:FeSb2=7:3) are relatively lower than those of bulk FeSb2. The ZT values of bulk FeSb2 sample are lower than those of the composite (CoSb3:FeSb2=7:3), that of the later increases with temperature rising at 100~500°C, the maximum value is up to 0.1647.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

3741-3744

Citation:

Online since:

July 2011

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. L. Cui, X. B. Zhao, W. M. Zhao: Materials Science and Engineering B, Vol. 94, Iss. 2-3, 1 Jun. 2002, pp.223-228.

Google Scholar

[2] V.B. Muñoz, L.E. Murr, D. Nemir: Materials Characterization, Vol. 59, Iss. 9, Sep. 2008, pp.1258-1272.

Google Scholar

[3] P.L. Ci, J. Shi, F. Wang: Materials Letters, Vol. 65, Iss. 11, 15 Jun. 2011, pp.1618-1620.

Google Scholar

[4] C.N. Liao, L.C. Wu: Journal of Alloys and Compounds, Vol. 490, No. 1-2, (2010), pp.468-471.

Google Scholar

[5] J.E. Rodríguez, L.C. Moreno: Materials Letters, Vol. 65, Iss. 1, 15 Jan. 2011, pp.46-48.

Google Scholar

[6] R.B. Song, T. Aizawa, J.Q. Sun: Materials Science and Engineering: B, Vol. 136, Iss. 2-3, 25 Jan. 2007, pp.111-117.

Google Scholar

[7] J.F. Li, S. Tanaka, T. Umeki: Sensors and Actuators A: Physical, Vol. 108, Iss. 1-3, 15 Nov. 2003, pp.97-102.

Google Scholar

[8] H. Liu, J.Y. Wang: Functional Materials of China, Vol. 31, No. 2 (2000): 116-123.

Google Scholar