The Study of Divalent Metal Ion Catalysts on Phenol-Formaldehyde Resol Resins

Article Preview

Abstract:

The curing characteristic of phenol-formaldehyde resol resins catalyzed with magnesium hydroxide, calcium hydroxide and barium hydroxide was studied in this study.The effects of catalysts on chemical structure of phenol formaldehyde resin was investigated by fourier transform infrared.The results indicated that divalent metal ions catalysts played an important role influence both the cure rate and cure time.Phenol formaldehyde resin catalysed by diffierent catalysts showed diffierent addition of formaldehyde onto ortho positions of phenolic rings.The order of the divalent metal ions effectiveness studied in alkaline conditions is calcium hydroxide, barium hydroxide and magnesium hydroxide.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

818-821

Citation:

Online since:

July 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. Knop and L.A. Pilato,Phenolic Resins.Springer-Verlag, Berlin,1985.

Google Scholar

[2] P. Luukko, L. Alvila, T. Holopainen, J. Rainio, T.T. Pakkanen: Journal of Applied Polymer Science Vol. 82 (2001), pp.258-262.

DOI: 10.1002/app.1846

Google Scholar

[3] T. Holopainen, L. Alvila, P. Savolainen, T.T. Pakkanen: Journal of Applied Polymer Science Vol. 91 (2004), pp.2942-2948.

Google Scholar

[4] A. Pizzi: Journal of Applied Polymer Science Vol. 24 (1979), p.1247–1255.

Google Scholar

[5] Yunyun Zhang, Yifan Zhang, Liangjia He, Zhifang Zhou: Journal of Adhesion Science and Technology Vol. 21 (2007), pp.833-839.

Google Scholar

[6] Liangjia He, Renlu Han, Yifan Zhang: Journal of Adhesion Science and Technology Vol. 23 (2009), pp.1639-1645.

Google Scholar

[7] K. Roczniak, T.Biernacka, M. Skarzynski: Journal of Applied Polymer Science Vol. 28 (1983), pp.531-542.

Google Scholar

[8] H.L. Bender, A.G. Farnham, J.W. Guyer, F.N. Apel, T.B. Bibb: Industrial & Engineering Chemistry Vol. 44 (1952), pp.1619-1629.

Google Scholar

[9] A. Fukuda, K. Hasegawa, Y. Kawaguchi, H. Horiuchi: Journal of Applied Polymer Science Vol. 30 (1985), p.3943–3952.

Google Scholar

[10] M. Duval, B. Bloch, S. Kohn: Journal of Applied Polymer Science Vol. 16 (1972), pp.1585-1602.

Google Scholar

[11] G. Astarloa-Aierbe, J.M. Echeverria, I. Mondragon: Polymer Vol. 40 (1999), pp.5873-5878.

DOI: 10.1016/s0032-3861(98)00816-7

Google Scholar

[12] M. Rama Rao, S. Alwan, K.J. Scariah, K.S. Sastri: Journal of Thermal Analysis Vol. 49 (1997), pp.261-268.

Google Scholar