Structure Studies on Order Assemblage of CadmiumII Isophthalicacid Benzimidazole Complexes

Guang Hui Wang; Da Jun Song; Hong Xiao  Tian; Jian Gao; Yu Liu

doi:10.4028/www.scientific.net/AMM.713-715.2872

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 713-715Structure Studies on Order Assemblage of CadmiumII...

Structure Studies on Order Assemblage of Cadmium^II Isophthalicacid Benzimidazole Complexes

Abstract:

The Cadmium^II Isophthalicacid Benzimidazole complex [Cd₂(C₈H₄O₄)₂ (C₇H₆N₂)₄(H₂O)₃], Triqua-bis (isophthalicacidato-O,O')-tetra (benzimidazole) bis (Cadmium^II),the Cd^II atom is coordinated by two isophthalicacid anions and two benzimidazole and one water molecule in a distorted octahedral configuration with six-coordinations geometry. And one isophthalicacid ligand chelates to the Cd^II atom through its one carboxylic O atoms, but the other isophthalicacid ligand chelates to the Cd^II atom through its two carboxylic O atoms. The same as another Cd^II atom. So we get a Binuclear Cd^I^I metal complexe. The fact clearly suggests not so much significant contribution from the electrostatic interaction in the Cd-O bonding in bidentate Binuclear Cd^II metal complexes as we gotten in mononuclear Mn^II metal complexes. Adjacent complex link to each other via hydrogen bonds forming the three-dimensional supramolecular structure.

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Applied Mechanics and Materials (Volumes 713-715)

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2872-2875

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.713-715.2872

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Online since:

January 2015

Authors:

Guang Hui Wang, Da Jun Song, Hong Xiao Tian, Jian Gao, Yu Liu*

Keywords:

Binuclear, Cadmium^II Isophthalicacid Benzimidazole Complex, Electrostatic Interaction, Photosystem Ii, Supramolecular Structure

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