Synthesis and Photoelectric Properties of Donor-Acceptor-Donor Molecule Containing Perylene Diimide

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In this paper, a novel perylene diimide derivative 1, 7-bis (N, N-bis (4-phenyl) aniline) perylene diimide (PDI-TPA) was synthesized and characterized by IR spectroscopy, 1H NMR and elemental analysis. Besides, solubility and photoelectric properties of PDI-TPA were studied. Results were shown that PDI-TPA exhibited an excellent solubility in common solvents. The absorption bands spanned a wide range of the visible spectra and optical band gap was 1.68 eV. In addition, PDI-TAP exhibited an ambipolar behavior, the highest occupied molecular orbital (HOMO) energy level and the lowest unoccupied molecular orbital (LUMO) energy level were-5.64 eV and-3.94 eV, respectively.

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December 2014

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