Effect of Chitosan-Grafted-Poly (Methyl Methacrylate) Content on Mechanical Properties and Thermal Degradation of Poly (Vinyl Chloride) Composites

Article Preview

Abstract:

The graft copolymerization was carried out under nitrogen atmosphere using the free radical initiation technique. The blend formulations were first dry blended using a mixer before being milled into sheets on a two-roll mill at 170°C, and then hot pressed into composites specimens at 175°C for 10 min. The objective of this study to investigate the mechanical and thermal properties of PVC blends. The flexural strength and modulus of ungrafted composites increased with increasing filler content from 2 to 10 part per hundred resin (phr) while the grafted composites also increased only from 2 to 6 phr filler content. The flexural modulus of ungrafted was higher compared to the grafted composites whereas the grafted showed good flexural strength than ungrafted composites. The impact strength of both composites decreased with increasing filler content but the ungrafted composites showed good toughness than grafted composites. The thermal stability of both composites increased compared to unfilled PVC.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

3-7

Citation:

Online since:

February 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Mengeloglu, F. and L.M. Matuana, Foaming of rigid PVC/wood-flour composites through a continuous extrusion process. Journal of Vinyl and Additive Technology, 2001. 7(3): pp.142-148.

DOI: 10.1002/vnl.10282

Google Scholar

[2] Radhakumary, C., et al., Biopolymer composite of chitosan and methyl methacrylate for medical applications. Trends Biomater. Artif. Organs, 2005. 18(2): pp.117-124.

Google Scholar

[3] Konaganti, V.K., et al., Adsorption of anionic dyes on chitosan grafted poly (alkyl methacrylate) s. Chemical Engineering Journal, 2010. 158(3): pp.393-401.

DOI: 10.1016/j.cej.2010.01.003

Google Scholar

[4] Lagos, A. and J. Reyes, Grafting onto chitosan. I. Graft copolymerization of methyl methacrylate onto chitosan with Fenton's reagent (Fe2+−H2O2) as a redox initiator. Journal of Polymer Science Part A: Polymer Chemistry, 1988. 26(4): pp.985-991.

DOI: 10.1002/pola.1988.080260403

Google Scholar

[5] Abu Bakar, A., N.S. Nik Mat, and M.K. Isnin, Optimized conditions for the grafting reaction of poly (methyl methacrylate) onto oil-palm empty fruit bunch fibers. Journal of Applied Polymer Science, 2008. 110(2): pp.847-855.

DOI: 10.1002/app.28540

Google Scholar

[6] Shah, B.L., et al., Effects of wood flour and chitosan on mechanical, chemical, and thermal properties of polylactide. Polymer Composites, 2008. 29(6): pp.655-663.

DOI: 10.1002/pc.20415

Google Scholar

[7] Zhu, A., et al., PMMA-grafted-silica/PVC nanocomposites: Mechanical performance and barrier properties. Journal of Applied Polymer Science, 2008. 108(4): pp.2189-2196.

DOI: 10.1002/app.27863

Google Scholar

[8] Hassan, A., N.I.S.M. Yusoff, and A. Abu Bakar, Effect of poly (methyl methacrylate)-grafted-talc content on mechanical properties and thermal degradation of poly (vinyl chloride) composites. (2012).

DOI: 10.1515/polyeng-2012-0009

Google Scholar

[9] Hammiche, D., et al., Effects of some PVC-grafted maleic anhydrides (PVC-g-MAs) on the morphology, and the mechanical and thermal properties of (alfa fiber)-reinforced PVC composites. Journal of Vinyl and Additive Technology, 2013. 19(4): pp.225-232.

DOI: 10.1002/vnl.21317

Google Scholar

[10] Abdolmohammadi, S., et al., Enhancement of Mechanical and Thermal Properties of Polycaprolactone/Chitosan Blend by Calcium Carbonate Nanoparticles. International Journal of Molecular Sciences, 2012. 13(4): pp.4508-4522.

DOI: 10.3390/ijms13044508

Google Scholar