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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 792In Situ Studies of Molecular Self-Assembling...

In Situ Studies of Molecular Self-Assembling during the Formation of Ion-Conducting Membranes for Fuel Cells

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Abstract:

In present work a new setup for in situ studies of molecular self-assembling process for fabrication of ion-conducting membranes for “green” fuel cells was developed. Due to compactness, this unique setup can be used on the synchrotron beamlines. The GISAXS and optical microscopy data have shown the effectiveness of the control of molecular architecture by impact of high temperature, UV-irradiation and solvent vapors.

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Periodical:

Applied Mechanics and Materials (Volume 792)

Pages:

623-628

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.792.623

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Online since:

September 2015

Authors:

Kseniia N. Grafskaia*, Denis V. Anokhin, Jaime J. Hernandez Rueda, Dmitriy A. Ivanov

Keywords:

Ion-Conducting Membrane, Liquid-Crystalline Polymer, Photo Induced Isomerization, Self-Organization

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. X. Lu, B. Panchapakesan, Photomechanical responses of carbon nanotube/polymer actuators Nanotechnology 18 (2007) 305502.

DOI: 10.1088/0957-4484/18/30/305502

[2] C. Z. Wu, J. Feng, L. L. Peng, Y. Ni, H. Y. Liang, L. H. He, Y. Xie, Large-area graphene realizing ultrasensitive photothermal actuator with high transparency: new prototype robotic motions under infrared-light stimuli, J. Mater. Chem. 21 (2011).

DOI: 10.1039/c1jm13311j

[3] J. J. Liang, Y. F. Xu, Y. Huang, L. Zhang, Y. Wang, Y. F. Ma, F. F. Li, T. Y. Guo, Y. S. Chen, Infrared-Triggered Actuators from Graphene-Based Nanocomposites, J. Phys. Chem. C 113 (2009) 9921–9927.

DOI: 10.1021/jp901284d

[4] A. Bobrovsky, V. Shibaev, M. Cigl, V. Hamplová, F. Hampl, G. Elyashevitch, Photochromic LC-polymer composites containing azobenzene chromophores with thermally stable Z-isomer, Journal of Materials Chemistry 2 (2014) 4482-4489.

DOI: 10.1039/c4tc00015c

[5] O. Sinitsyna, A. Bobrovsky, I. Yaminsky, V. Shibaev, Peculiarities and mechanism of surface topography changes in photochromic cholesteric oligomer-based films, Colloid and Polymer Science 292 7 (2014) 1567-1575.

DOI: 10.1007/s00396-014-3199-7

[6] A. Bobrovsky, N. Boiko, V. Shibaev, The peculiarities of the photoorientation processes in azobenzene-containing liquid crystalline homo- and co-dendrimers, Polymer 56 (2015) 263-270.

DOI: 10.1016/j.polymer.2014.11.046

[7] M. Rosenthal, L. Lei, J.J. Hernandez, X. Zhu, D.A. Ivanov, M Moeller, A Diacetylene-Containing Wedge-Shaped Compound: Synthesis, Morphology, and Photopolymerization, Chemistry - A European Journal 19 13 (2013) 4300-4307.

DOI: 10.1002/chem.201203240

[8] L. Lei, M. Rosenthal, H. Zhang, J.J. Hernandez, M. Drechsler, K.H. Phan, S. Ruetten, X. Zhu, D.A. Ivanov, M. Moeller, Light-Switchable Vesicles from Liquid-Crystalline Homopolymer-Surfactant Complexes, Angewandte Chemie - International Edition 51 46 (2012).

DOI: 10.1002/anie.201205660

[9] C. Riekel, C. E. Di, M. Reynolds, M. Burghammer, M. Rosenthal, D. Doblas, D.A. Ivanov, Thermal Transformations of Self-Assembled Gold Glyconanoparticles Probed by Combined Nanocalorimetry and X-ray Nanobeam Scattering, Langmuir : the ACS journal of surfaces and colloids 31 11 (2015).

DOI: 10.1021/la504015e

[10] Y. Chen, M.D. Lingwood, M. Goswami, B.E. Kidd, J.J. Hernandez, M. Rosenthal, D.A. Ivanov, J. Perlich, H. Zhang, X. Zhu, M. Moeller, L.A. Madsen, Humidity-Modulated Phase Control and Nanoscopic Transport in Supramolecular Assemblies, Journal of Physical Chemistry B 118 11 (2014).

DOI: 10.1021/jp409266r

[11] H. Zhang, L. Li, M. Möller, X. Zhu, J.J. Hernandez, M. Rosenthal, D.A. Ivanov, From Channel-Forming Ionic Liquid Crystals Exhibiting Humidity-Induced Phase Transitions to Nanostructured Ion-Conducting Polymer Membranes, Advanced Materials 25 26 (2013).

DOI: 10.1002/adma.201205097

[12] E. Mabrouk, D. Cuvelier, F. Brochard-Wyart, P. Nassoy, M. H. Li, Bursting of sensitive polymersomes induced by curling, Proc. Natl. Acad. Sci. USA 106 (2009) 7294-7298.

DOI: 10.1073/pnas.0813157106

[13] P. Han, N. Ma, H. Ren, H. Xu, Z. Li, Z. Wang, X. Zhang, Oxidation-Responsive Micelles Based on a Selenium-Containing Polymeric Superamphiphile, Langmuir 26 (2010) 14414 – 14418.

DOI: 10.1021/la102837a

[14] X. Zhu, B. Tartsch, U. Beginn, M. Möller, Wedge-Shaped Molecules with a Sulfonate Group at the Tip—A New Class of Self-Assembling Amphiphiles, Chem. Eur. J. 10 (2004) 3871-3878.

DOI: 10.1002/chem.200400050

[15] X. Zhu, U. Beginn, M. Möller, R. I. Gearba, D. V. Anokhin, D. A. Ivanov, Self-Organization of Polybases Neutralized with Mesogenic Wedge-Shaped Sulfonic Acid Molecules: An Approach toward Supramolecular Cylinders, J. Am. Chem. Soc. 128 51 (2006).

DOI: 10.1021/ja065968v