Preparation of Pb(II)-Imprinted-Carboxymethyl Chitosan-Pectin-BADGE Film as Sorbent for Pb(II) Ion

Abstract:

Cross-linked metal-imprinted Carboxymethyl Chitosan-Pectin (CMC-Pec) were prepared from CMC and pectin, using Pb (II) ion as a template and Bisphenol A diglycidil ether (BADGE) as the cross-linking agent. The film was prepared in order to obtain a selective adsorbent for Pb (II) ion. The film was characterized using infrared (IR) spectroscopy. The result showed that the active group of the Pb (II)-imprinted CMC-Pec-BADGE film was hydroxyl group (-OH) and carboxylic (-COOH) as indicated by IR peaks at the wave number 3300-3600 cm^-1 and 1600-1800 cm^{- 1}, respectively. The Pb (II) adsorption capacity of the Pb (II)-imprinted CMC-Pec-BADGE film was 12.18 mg/g. The film showed a selective adsorption for Pb (II) metal ions compared to the adsorption of Zn (II) and Cu (II) in mole ratio of 1: 1: 1.

• Periodical: Applied Mechanics and Materials (Volume 798)
• Pages: 384-389
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.798.384
• Online since: October 2015
• Authors: Budi Hastuti*, Mudasir Mudasir, Dwi Siswanta, Triyono Triyono
• Keywords: BADGE, CMC, Imprinted Pb, Ion Pb, Pectin

References

[1] F. Fu and Q. Wang. A review. J. Environmental Management 92 (2011) 40-418.

[2] Y.Q. Tan, M and Chen, Y.M. Hao: Chem. Eng. J (2012) Vol 191, 104-111.

[3] L. Yuan and Y.S. Liu: Chem. Eng. J (2013) Vol 215-216, 432-439.

[4] B. Liu, L. Lv, X. Meng, G. Yu, D. Wang : Chem. Eng. J (2013) Vol. 220, 412-419.

[5] S. Schiewer and S.B. Patil: Bioresource Technology (2008) Vol. 99, 1896-(1903).

[6] M.M. Fares, Y.R. Tahboub, T. Samar, Khatatbch, Y.M. Abdul-Haija : J. Polym. Environ. (2011) Chem. Eng. J (2013)Vol. 19, 431-439.

[7] L.A. Kupchik, N.T. Kartel, E.S. Bogdanov, O.V. Bogdanov and M.P. Kupchik : J. Macromol. Chem and Polym. Mater (2006) Vol 79, 457-460.

DOI: 10.1134/s1070427206030256

[8] T. Yoshimura., K. Sengoku, and R. Fujioka (2005) Polym. Bull., 55, 123-129.

[9] G. Crimi : Progress in Polymer Science (2005) Vol 30, 38-70.

[10] A. Masykur, S.J. Santosa, D. Siswanta and Jumina : Indo J. Chem (2014), Vol. 14 (1), 63-70.

[11] V.K. Mourya, N.N. Inamdara and A. Tiwarib : Adv. Mat. Lett. (2010). Vol 1(1), 11-33.

[12] W.W. Wai, F.M. Abbas, Al Karkhi, A.M. Easa: Carbohydrate Polymers (2010) Vol. 79, 584-589.

[13] S. Sun and A. Wang : J. Hazard. Mater ( 2006) Vol 131, 103-111.

[14] Chen Hwang, Cheng-Yu, Y., Chia-Yun C., Chia-When, C : Journal of Hazardous Materials(2009) Vol. 163, 1068-1075.

[15] C. Bernable, W. Peniche and Argueles-Monal: Polymer Bulletin (2005) Vol. 55, 367-375.