Synthesis and Characterization of Cobalt-Nickel Nanowires Formed under External Magnetic Field

Article Preview

Abstract:

Cobalt-nickel (Co-Ni) nanowires were formed by electroless deposition in ethylene glycol under external magnetic field. The effects of initial Co (II) and Ni (II) concentration on the surface and morphology of the synthesized nanowires were investigated by x-ray diffraction (XRD) and scanning electron microscope (SEM) respectively. An increase in the Co (II) concentration resulted in increase in diameter of the nanowires. However, the length of nanowires was observed to decrease. Higher Co (II) concentration resulted in a mixture of hexagonal close-packed and face-centered cubic Co-Ni nanowires. X-ray diffraction revealed that crystal growth occurred when the nanowires are annealed at 653 K for 10h.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

120-124

Citation:

Online since:

October 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Panday, Sudhakar et. al. Synthesis of nanocrystalline Co–Ni alloys by precursor approach and studies on their magnetic properties., Journal of Magnetism and Magnetic Materials, Science Direct, 2011. http: /www. sciencedirect. com.

DOI: 10.1016/j.jmmm.2011.04.006

Google Scholar

[2] Skomski, R. et al. Magnetic localization in transition-metal nanowires,. Phys. Rev., B 62 (2000) 3900.

Google Scholar

[3] Balela, M.D. Syntheses of Metallic Cobalt Nanoparticles and Nanowires by Electroless Deposition., Kyoto University Research Information Repository, 2011. http: /hdl. handle. net/2433/151979.

Google Scholar

[4] Gubin, S. P., et. al. Magnetic Nanoparticles: Preparation, Structure and Properties, Russ. Chem. Rev., 74, 489 (2005).

Google Scholar

[5] Kawamori, Makoto et al. Nickel Alloying Effect on Formation of Cobalt Nanoparticles and Nanowires via Electroless Deposition under a Magnetic Field,. Journal of the Electrochemical Society (2011), 159(2): E37-E44, 2011-(2012).

DOI: 10.1149/2.062202jes

Google Scholar

[6] Schmuki, Patrikand Virtanen, Sannakaisa(Editors). Electrochemistry at the Nanoscale. New York: Springer Science, 2009. Print.

Google Scholar

[7] Kawamori, Makoto et al. Electrochemical Study on the Synthesis Process of Co-Ni Alloy Nanoparticles via Electroless Deposition,. Journal of The Electrochemical Society, 157 (5) E92-E97, 2010, The Electrochemical Society.

DOI: 10.1149/1.3352893

Google Scholar

[8] Kawamori, Makoto et al. Formation of Nickel Nanowires ViaElectroless Deposition Under a Magnetic Field,. Journal of The Electrochemical Society, 158 (8) E79-E83, 2011, The Electrochemical Society.

DOI: 10.1149/1.3596703

Google Scholar

[9] Zhang, Liying ; Lan, Tianmin; Wang, Wei, Jian Liangmin; Zhi, Yangand Zhi, Yafei Zhang. Template-free Synthesis of One-dimensional Cobalt Nanostructures by Hydrazine Reduction Route,. Nanoscale Research Letter, 6 , 2011, Springer Open Journal.

DOI: 10.1007/s11671-010-9807-7

Google Scholar

[10] Zhang, Ya-jing ; Zhang, Ying ; Wang, Zhen-hua; Li, Da; Cui, Tie-yu ; Liu, Wei and Zhang, Zhi-dong . Controlled Synthesis of Cobalt Flowerlike Architectures by a Facile Hydrothermal Route,. European Journal of Inorganic Chemistry, 2733-2738, (2008).

DOI: 10.1002/ejic.200800137

Google Scholar

[11] Petit, C.; Wang, Z. L. and Pileni, M. P. Seven-Nanometer Hexagonal Close Packed Cobalt Nanocrystals for High-Temperature Magnetic Applications through a Novel Annealing Process,. Journal of Physical Chemistry, 109(12) 15309-15316, American Chemical Society. q.

DOI: 10.1021/jp052487+

Google Scholar

[12] R. Palmer and M. Ladd. Structure Determination by X-ray Crsytallography: Analysis by X-rays and Neutrons 5thEd. Ch. 12. Springer Science and Business Media, New York, (2013).

Google Scholar

[13] Balela, M.D., et. al. Fabrication of Cobalt Nanowires by Electroless Deposition under External Magnetic Field,. Journal Of The Electrochemical Society (2011), 158(4): D210-d216, (2011).

DOI: 10.1149/1.3545065

Google Scholar

[14] Lackner, Maximillian; et. al. Combustion Synthesis: Novel Route to Novel Materials. Chapter 18, Bentham Science, Dubai, (2010).

Google Scholar

[15] Glaspell, G; et. al. Formation of Cobalt Nitrate Hydrate, Cobalt Oxide, and Cobalt Nanoparticles Using Laser Vaporization Controlled Condensation., Journal of Physical Chemistry, 108: 9604-9607, 2004, American Chemical Society.

DOI: 10.1021/jp0370831

Google Scholar

[16] Han, S. et al. Characterization of Ni nanowires after annealing., Materials Letters, Science Direct, 2006. http: /www. sciencedirect. com.

Google Scholar

[17] International Center for Diffraction Data. JCPDS 04-0850. Prentice Hall, 2004. http: /www. pearson-studium. de.

Google Scholar