Effects of Ti(C,N) Nanoparticles on Mechanical Properties of the Si3N4 Ceramics

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Abstract:

Si3N4-Ti(C,N) nanocomposites fabricated by vacuum hot pressing with Al2O3 and Y2O3 as additives were investigated. The results showed that the α-Si3N4 phase converted completely into whisker-shaped β-Si3N4 grains after vacuum sintering at 1700°C. Suitable addition and well dispersion of the Ti(C,N) particles can restrained the lateral growth of the β-Si3N4 grains, increasing aspect ratio of the β-Si3N4 grains and improving bending strength of the composites. Fracture toughness of the composites is higher than that of the β-Si3N4 ceramics, and the main toughening mechanism is crack bridging due to the higher aspect ratio of the β-Si3N4 grains.With the addition of 1vol% of Ti(C,N), the composite has a relative density of 99.31%, Vicker’s hardness of 15.9 GPa, bending strength of 993 MPa, and fracture toughness of 9.9 MPa·m1/2.

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119-122

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July 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Ekstrorn, K. Mackenzie, M. Ryan, Phases occurring in the Si3N4-YN system, Journal of Materials Chemistry. 7(1997)505-509.

Google Scholar

[2] G. Woetting, B. Caspers, E. Gugel, Hightemperature properties of SiC-Si3N4 particle composites. Journal of Engineering for Gas Turbines and Power, 8(2000)122-124.

DOI: 10.1115/1.483171

Google Scholar

[3] F.Q. Yan, F. Chen, Q. Shen, Spark plasma sintering of α–Si3N4 ceramics with MgO–Al2O3 as sintering additives, Key Engineering Materials. 176(2007)351-356.

DOI: 10.4028/www.scientific.net/kem.351.176

Google Scholar

[4] G. A. Swift, E. Ustundag, B. Clausen, High-temperature elastic properties of in situ-reinforced Si3N4, Applied Physics Letters. 82(2003)1039-1042.

DOI: 10.1063/1.1554478

Google Scholar

[5] Z. J. Lu, X. AI, J. Zhao, Mechanical properties and microstructure of Si3N4-TiC nanocomposites, J. Mater. Sci. Technol. 21(2005)899-902.

Google Scholar

[6] R. M. Yin, J. L. Fan, X. Liu, Effect of Mg-Y oxides on the microstructure and properties of Fe–Mo/Si3N4 cermet, Chinese Journal of Materials Research. 24(2010)232-238.

Google Scholar

[7] J. S. Ha, C. S. Kim, D. S. Cheong, Processing and properties of Al2O3/ Si3N4 nanocomposite coated alumina by slurry dipcoating, Journal of Materials Science Letters. 17(1998)747-749.

Google Scholar

[8] X. W. Zhu, Y. Zhou, H. R. Kiyoshi, Effects of processing method and additive composition on microstructure and thermal conductivity of Si3N4 ceramics, Journal of the European Ceramic Society. 26(2006)711-718.

DOI: 10.1016/j.jeurceramsoc.2005.07.027

Google Scholar

[9] Xiong J, Zhang Y K, Shen B L, et al. The Preparing and performance of superfine TiCN cermet. Powder Metall Techol 23(2004)164-167.

Google Scholar

[10] Ahn S Y, Kang S. Effect of WC particle size on microstructure and rim composition in the Ti(C0. 7N0. 3)-WC-Ni system, Scripta Materialia. 55(2006)1015–1018.

DOI: 10.1016/j.scriptamat.2006.08.008

Google Scholar