Studies of Dielectric Permittivity of Y₂NiMnO₆ Ceramics for DC Bias at Various Temperatures

Abstract:

The dielectric permittivity (ε) of Y₂NiMnO₆ ceramics prepared by sintering at 1400 °C over 6 to 24 hours was investigated. The response of the ceramics was measured from 1 kHz to 3 MHz, with the influence of a fixed dc bias from 0 to 1.5 V and temperature from 40 °C to -60 ^oC. Increasing dc bias was found to reduce ε' at low frequencies, while at higher frequencies the dc bias had less influence on ε'. At 40 °C a sharp transition from high to low ε' occurred starting at ~100 kHz, as the temperature of the ceramic was lowered, the transition shifted to lower frequencies. This behaviour is attributed to the charge ordering of Ni²⁺ and Mn⁴⁺ ions and the thermal effect on the ions energy.

• Periodical: Applied Mechanics and Materials (Volume 866)
• Pages: 272-276
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.866.272
• Online since: June 2017
• Authors: Naphat Albutt*, Suejit Pechprasarn, Phimonkhae Chobdee, Thanapong Sareein
• Keywords: Ceramics, Composite, Dielectric Permittivity

References

[1] S. Kumar, G. Giovannetti, J. van den Brink and S. Picozzi, Theoretical prediction of multiferroicity in double perovskite Y2NiMnO6, Phys. Rev. B82 (2010) 134429.

[2] Y.Q. Lin, X.M. Chen and X.Q. Liu, Relaxor-like dielectric behavior in La2NiMnO6 double perovskite ceramics, Solid State. Com. 149 (2009) 784-787.

DOI: 10.1016/j.ssc.2009.02.028

[3] B. Jeroen van den and D.I. Khomskii, Multiferroicity due to charge ordering, J. Phys. Condens. Matter. 20 (2008) 434217.

DOI: 10.1088/0953-8984/20/43/434217

[4] M.P. Singh, K.D. Truong, S. Jandl and P. Fournier, Magnetic properties and phonon behavior of Pr2NiMnO6 thin films, Appl. Phys. Lett. 98 (2011) 162506.

DOI: 10.1063/1.3575564

[5] K. Yoshii, N. Ikeda and M. Mizumaki, Magnetic and dielectric properties of the ruthenium double perovskites La2MRuO6 (M=Mg, Co, Ni, and Zn), Phys. status solidi(a). 203 (2006) 2812-2817.

DOI: 10.1002/pssa.200669549

[6] S. Daengsakul, C. Mongkolkachit, C. Thomas, S. Siri, I. Thomas, V. Amornkitbamrung and S. Maensiri, A simple thermal decomposition synthesis, magnetic properties, and cytotoxicity of La0. 7Sr0. 3MnO3 nanoparticles, Appl. Phys. A96 (2009) 691-699.

DOI: 10.1007/s00339-009-5151-0

[7] T. Siritanon, N. Chathirat, Ch. Masingboon and T. Yamwong, Synthesis, characterization, and dielectric properties of Y2NiMnO6 ceramics prepared by a simple thermal decomposition route, J Mater Sci: Mater Electron. 25 (2014) 1361-1368.

DOI: 10.1007/s10854-014-1735-3

[8] P. Deeyai,T. Sareein, B. Putasaeng and N. Chathirat, Dielectric properties of Y2NiMnO6 ceramics at various sintering times and temperatures, AMM. 804. 16 (2015) 16-20.

DOI: 10.4028/www.scientific.net/amm.804.16

[9] P. Deeyai,T. Sareein, B. Putasaeng and N. Chathirat, Study behavior of XPS spectra of Ni, Mn, Y and O in Y2NiMnO6 ceramics, AMM. 804. 16 (2015) 97-103.

DOI: 10.4028/www.scientific.net/amm.804.97