Poly Acrylic Acid Superabsorbent Hydrogel for Hygiene Materials

Article Preview

Abstract:

Poly acrylic acid (PAA) was synthesized by solution polymerization. We analysed that MBA dosage, acrylic acid percentage, neutralization degree and surface crosslink have affections on PAA, mainly about three properties (including 0.9%NaCl solution's absorptivity, absorptivity under 2068Pa, and holding ability of moisture). The experimental evidence obtained that lower acrylic acid percentage is helpful to these three properties. Indexes increase at first and then decrease with neutralization degree raise. MBA dosage is against to absorptivity and retention capability, but useful to absorptivity under pressure. Scanning electron microscopy (SEM) was used to observe the surface of the PAA powder, and prove that surface crosslink promote form a kind of honeycomb structure. Under the optimum synthetic conditions, the absorptivity of 0.9%NaCl solution is 58.8 times, retention capability is 38.4 times, and absorptivity under 2068Pa is 33.6 times.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

7-10

Citation:

Online since:

August 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Cheng, Z., Li, J., Yan, J., Kang, L., Ru, X. and Liu, M. (2013), Synthesis and properties of a novel superabsorbent polymer composite from microwave irradiated waste material cultured Auricularia auricula and poly (acrylic acid-co-acrylamide). J. Appl. Polym. Sci., 130: 3674–3681

DOI: 10.1002/app.39621

Google Scholar

[2] Zhang, J. P., Li, A. and Wang, A. Q. (2005), Study on superabsorbent composite. V. Synthesis, swelling behaviors and application of poly(acrylic acid-co-acrylamide)/sodium humate/attapulgite superabsorbent composite. Polym. Adv. Technol., 16: 813–820

DOI: 10.1002/pat.657

Google Scholar

[3] Murali Mohan, Y., Keshava Murthy, P. S., Sreedhar, B. and Mohana Raju, K. (2006), Swelling and thermal characteristics of pH sensitive crosslinked poly(acrylamide-co-calcium methacrylate) superabsorbent copolymers. J. Appl. Polym. Sci., 102: 1–12

DOI: 10.1002/app.23562

Google Scholar

[4] Pourjavadi, A., Samadi, M. and Ghasemzadeh, H. (2008), Fast-swelling Superabsorbent Hydrogels from Poly(2-hydroxy ethyl acrylate-co-sodium acrylate) Grafted on Starch. Starch/Stärke, 60: 79–86

DOI: 10.1002/star.200700666

Google Scholar

[5] Buchholz, F. L. 2006. Superabsorbent Polymers. Encyclopedia of Polymer Science and Technology.

Google Scholar

[6] Kabiri, K., Omidian, H., Zohuriaan-Mehr, M. J. and Doroudiani, S. (2011), Superabsorbent hydrogel composites and nanocomposites: A review. Polym Compos, 32: 277–289

DOI: 10.1002/pc.21046

Google Scholar

[7] P.J. Flory,The principles of polymer Chemistry[M],Cornell University Press,Ithaca,New York,1954.

Google Scholar