The Leaching Behaviours of Chalcopyrite with Distinct Genetic Types

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Abstract:

The copper extraction yield from chemical leaching of chalcopyrite depends on temperature, pH, and the oxidation-reduction potential (ORP), as well as on the different genetic type of the chalcopyrite used. The chemical leaching characteristics of chalcopyrite from marine volcanic type and porphyry type were studied. It was found that the intermediates of marine volcanic chalcopyrite and porphyry chalcopyrite elucidated from the MLA were elemental sulphur and non-stoichiometric minerals, such as Cu3.5Fe4S2.5, Cu5Fe4S and Cu3.5Fe1.5S5. The results suggested that the main difference between marine volcanic chalcopyrite and porphyry chalcopyrite is the rates of copper and iron ions dissolution from chalcopyrite crystal lattice.

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Advanced Materials Research (Volumes 1033-1034)

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1288-1291

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October 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Rivadeneira, J. Introduction. Mining innovation in Latin America Report. Publication via on-line (http: /www. mininginnovation. cl/content. htm). Santiago, Chile, 6-7. (2006).

Google Scholar

[2] Dutrizac, J.E. The kinetics of dissolution of chalcopyrite in ferric ion media. Metall. Trans. B 9B, 431-439. (1978).

DOI: 10.1007/bf02654418

Google Scholar

[3] Hiroyoshi, N., Hirota, M., Hirajima, T., Tsunekawa, M. A case of ferrous sulfate addition enhancing chalcopyrite leaching. Hydrometallurgy 47, 37-45. (1997).

DOI: 10.1016/s0304-386x(97)00032-7

Google Scholar

[4] Konishi, Y., Tokushige, M., Asai, S., Suzuki, T. Copper recovery from chalcopyrite concentrate by acidophilic thermophile Acidianus brierleyi in batch and continuous-flow stirred tank reactors. Hydrometallurgy 59, 271-282. ( 2001).

DOI: 10.1016/s0304-386x(00)00173-0

Google Scholar

[5] Vilcáez, J., Suto, K., Inoue, C. Bioleaching of chalcopyrite with thermophiles: Temperature–pH–ORP dependence. International Journal of Mineral Processing 88, 37-44. (2008).

DOI: 10.1016/j.minpro.2008.06.002

Google Scholar

[6] Fu, K.B., Lin, H., Mo, X.L., Dong, Y.B., Wang, H. Passivation of different genetic types of chalcopyrite bioleaching. Journal of Central South University 42, 3245-3250. (2011).

Google Scholar

[7] Bai, J., Wen, J.K., Huang, S.T., Wu, B., Yao, G.C. Renew on Bioleaching of Chalcopyrite with Different Mineralization. Chinese Journal of Rare Metals 36, 644-650. (2012).

Google Scholar

[8] Sandström, Å., Shchukarev A., Paul, J. XPS characterisation of chalcopyrite chemically and bio-leached at high and low redox potential. Mineral Engineering 18, 505-515. (2005).

DOI: 10.1016/j.mineng.2004.08.004

Google Scholar