Synthesis and Properties of Anionic Maleic Monoester Carboxylate Polymeric Surfactants

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Abstract:

Four anionic maleic monoester carboxylate polymeric surfactants were synthesized by the reaction of maleic anhydride with linear alcohols of different chain length in the ratio of 1:1.1 under 80 °C. Then the intermediate products were neutralized by sodium hydroxide at 60 °C to produce the final monomers. The structures of products were confirmed by FTIR. The surface tension was measured at 45 °C and the thermodynamic parameters were calculated. The results show that the polymeric surfactants possess low critical micelle concentration (CMC), high adsorption affinities and good surface and interfacial activity.

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Advanced Materials Research (Volumes 1033-1034)

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26-29

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October 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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