Synthesis of 3-O-Caffeoyl-Quinide Catalyzed by p-Toluenesulfonic Acid

Jun Wang; Sha Sha Wang; Xiang Yang Wu

doi:10.4028/www.scientific.net/AMR.1033-1034.39

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1033-1034Synthesis of 3-O-Caffeoyl-Quinide Catalyzed by...

Synthesis of 3-O-Caffeoyl-Quinide Catalyzed by p-Toluenesulfonic Acid

Abstract:

3-O-caffeoyl-quinide, a dehydration compound of 3-O-caffeoylquinic acid, was obtained using p-toluenesulfonic acid as a catalyst via esterification in traditional organic solvent and transesterification in ionic liquid, respectively. The quinide, identified by ¹H-NMR spectrum, was prepared as an intermediate product for the synthesis of 3-O-caffeoyl-quinide, and the products was identified by LC-MS. Results indicated that the developed purification method of quinide was much simple than before with a higher yield, and [Bmim][Tf₂N] was selected as the suitable reaction medium.

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Periodical:

Advanced Materials Research (Volumes 1033-1034)

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39-42

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.39

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Online since:

October 2014

Authors:

Jun Wang, Sha Sha Wang, Xiang Yang Wu*

Keywords:

3-O-Caffeoyl-Quinide, Ionic Liquid (IL), p-Toluenesulfonic Acid, Quinide

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References

[1] J. Wang, D. Q. Lu, Q. J. Sun, H. Zhao, X. Q. Ling and P. K. Ouyang: Chem. Eng. Sci. Vol. 78(2012), p.53.

Google Scholar

[2] A. Farah, T. Paulis, L. Trugo and P. Martin: J Agr. Food Chem. Vol. 53(2005), p.1505.

Google Scholar

[3] J. Wang, D. Q. Lu, Y. Liang, H. Zhao, M. Luo, X. Q. Ling and P. K. Ouyang: J. Sep. Sci. Vol. 35(2012), p.1379.

Google Scholar

[4] O. Frank, S. Blumberg, G. Krumpel and T. Hofmann: J. Agr. Food Chem. Vol. 56(2008), p.9581.

Google Scholar

[5] N. Kaiser, D. Birkholz, S. Colomban, L. Navarini and U. Engelhardt: J. Agr. Food Chem. Vol. 61(2013), p.6937.

Google Scholar

[6] T. Kondo, Y. Toyama and K. Yoshida: Tetrahedron Lett. Vol. 46(2005), 6645.

Google Scholar

[7] A. Kurata, Y. Kitamura, S. Irie, S. Takemoto, Y. Akai and Y. Hirota: J. Biotechnol. Vol. 148(2010), p.133.

Google Scholar

[8] M. Erbeldinger, A. Mesiano and A. Russell: J. Biotechnol. Progr. Vol. 16(2000), p.1129.

Google Scholar

[9] J. Wang, S. S. Gu, N. Pang, F. Q. Wang, F. A. Wu: J. Serb. Chem. Soc. Vol. 78 (2013), p.1023.

Google Scholar

[10] P. Huang, K. Sabbe, M. Pottie and M. Vandewalle: Tetrahedron Lett. Vol. 36(1995), p.8299.

Google Scholar

[11] A. Rechner, A. Pannala and C. Rice: Free Radical. Res. Vol. 35(2001), p.195.

Google Scholar

[12] P. Lozano, T. D, D. Carrié, M. Vaultier and J. Iborra: Biotechnol. Lett. Vol. 2 (2001), p.1529.

Google Scholar