Studies on Synthesis and Properties of Hydrophobic Brønsted Acidic Ionic Liquid

Article Preview

Abstract:

A hydrophobic Brønsted acidic ionic liquid 1-octyl-3-(butyl-4-sulfonate) imidazolium hydrogen sulfate ([BsImR8][HSO4]) was synthesized and characterized by fourier transform infrared (FT-IR), nuclear magnetic resonance (NMR), electron spray ionization mass spectrometry (ESI-MS) and thermogravimetry (TG). [BsImR8][HSO4] was used as an efficient catalyst for esterification of oleic acid with methanol to biodiesel. It was founded that [BsImR8][HSO4] exhibited high catalytic activity, which is near to that of H2SO4.It was ascribed to its strong Brønsted acidity. The catalyst could maintain high activity after five cycles of use.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1033-1034)

Pages:

70-75

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] E.Z. Min: J. Chem. Ind. Eng. Vol. 57 (2006), p.1739.

Google Scholar

[2] X. Ji and X.L. Xi: Renew. Energ. Vol. 5 (2002), p.16.

Google Scholar

[3] L. Zhang, M. Xian, Y.C. He, L.Z. Li, J.M. Yang, S.T. Yu and X. Xu: Bioresour. Technol. Vol. 100 (2009), p.4368.

Google Scholar

[4] P.H. Yu, Y. Tang, C.L. Zhang and Y.P. Jie: Chem. Ind. Eng. Prog. Vol. S1 (2010), p.64.

Google Scholar

[5] B. Zhen, H.S. Li, Y. Li and Q. Wu: J. Chem. Ind. Eng. Vol. 62 (2011), p.80.

Google Scholar

[6] Y.L. Gu, F. Shi and Y.Q. Deng: J. Mol. Catal. A-Chem. Vol. 212 (2004), p.71.

Google Scholar

[7] H.L. Xin, Q. Wu, M.H. Han, D.Z. Wang and Y. Jin: Appl. Catal. A. Vol. 292 (2005), p.354.

Google Scholar

[8] L.Y. Piao, X. Fu, Y.L. Yang, G.H. Tao and Y. Kou: Catal. Today Vol. 93 (2004), p.301.

Google Scholar

[9] K. Yoo, E.C. Burckle and P.G. Smirniotis: J. Catal. Vol. 211 (2002), p.6.

Google Scholar

[10] C.Z. Qiao, Y.F. Zhang, J.C. Zhang and C.Y. Li: Appl. Catal. A. Vol. 276 (2004), p.61.

Google Scholar

[11] H.P. Zhu, Y. Fan, J. Tang and M.Y. He: Green Chem. Vol. 5 (2003), p.38.

Google Scholar

[12] Y.L. Gu, F. Shi and Y.Q. Deng: J. Mol. Catal. A-Chem. Vol. 212 (2004), p.71.

Google Scholar

[13] D.C. Forbes and K.J. Weaver: J. Mol. Catal. A- Chem. Vol. 214 (2004), p.129.

Google Scholar

[14] K. Qiao and C. Yokoyama: Chem. Lett. Vol. 33 (2004), p.808.

Google Scholar

[15] F. Santamarta, P. Verdia and E. Tojo: Catal. Commu. Vol. 9 (2008), p.1779.

Google Scholar

[16] Y. Zhang, Y.W. Zhao and C.G. Xia: J. Mol. Catal. A-Chem. Vol. 306 (2009), p.107.

Google Scholar

[17] A.G. Ying, H.D. Liang, R.H. Zheng, C.H. Ge, H.J. Jiang and C.L. Wu: Res. Chem. Intermed. Vol. 37 (2011), p.579.

Google Scholar

[18] J.H. Shen, H. Wang, H.C. Liu, Y. Sun and Z.M. Liu: J. Mol. Catal. A-Chem. Vol. 280 (2008), p.24.

Google Scholar

[19] L.Y. Zhu, L.G. Chen, Y. Fu and Z.F. Liu: J. Log. Eng. Un. Vol. 25 (2009), p.50.

Google Scholar