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Preparation of Core-Shell Particles Consisted of Polysiloxane and Styrene-Butyl Methacrylate by High Internal Phase Emulsion

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Abstract:

A core-shell composite polymer was produced by the method of high internal phase emulsion polymerization. The continuous phase of emulsion contained styrene(St), butyl methacrylate(BMA), octamethylcylotetrasiloxane(D4), and azobisisobutyronitrile (AIBN) which worked as an initiator. The block copolymers with St, BMA, D4 units are particularly promising for surface modification and hydrophobicity. The core-shell structure is proved by the use of Transmission electron microscopy (TEM). In addition, the water contact angle increased with the increasing weight ratio of D4. The results show that the concentrated emulsion system has good stability and the water resistance of the polymer has been improved greatly.

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Periodical:

Advanced Materials Research (Volumes 1033-1034)

Pages:

996-1001

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.996

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Online since:

October 2014

Authors:

Shao Jin Jia*, Zhen Qi Zhang, Zhen Gang Ding, Xiao Tian Hou, Ping Kai Jiang

Keywords:

Butyl Methacrylate, Core-Shell, High Internal Phase Emulsion, Octamethylcyclotetrasiloxane, Water Absorption

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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