Study of the Hydrodesulphurization Process of Hydrogenate of Shubarkol Coal

Article Preview

Abstract:

This is a research on the hydrodesulphurization process of hydrogenate from the coal of Shubarkolsky deposit (Republic of Kazakhstan) in the presence of pyrite and natural zeolite. The rate constants for hydrodesulphurization process of the liquid products and Gibbs energy were calculated by the method of equilibrium kinetic analysis, which was necessary for improving the technological parameters for the hydrotreatment of liquid hydrogenation products. It is shown that the optimal time of the hydrodesulphurization process is 15-25 minutes. The sulfur content in the fraction up to 2000С is 0.043 %, and in a fraction of 200-3000С - 0.065 %, which indicates a high degree of hydrotreatment of the hydrogenate in the presence of the above mentioned catalyst.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

382-386

Citation:

Online since:

September 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Yulin, M.K., Meged, N.F., Golovchenko, S.V., Mezhlumova, A.I., Arifulin, A.S. Hydrogenation of thiophene on the zeolite catalysts. Solid Fuel Chemistry. 1 (1988) 85 – 88.

Google Scholar

[2] Radchenkov, E.D., Nefedov, B.K., Aliev, R.R. Industrial catalysts for the hydrogenation refining processes. M., Chemistry. (1987) 37-68.

Google Scholar

[3] Sidelnikova, V.G., Aliev, R.R. The role of the zeolite component in improving catalytic, operational and reclaiming properties of the hydrotreating catalysts. Solid Fuel Chemistry. 4 (1994) 14 - 18.

Google Scholar

[4] Breysse, M., Portefaix, J.J., Vrinat, M. Catalysis Today. 10, 1 (1991) 489-505.

DOI: 10.1016/0920-5861(91)80035-8

Google Scholar

[5] Malyshev, V.P., Shkodin, V.G. Equilibrium kinetic analysis of chemical processes. Alma-Ata: Gylym, 1990. 112.

Google Scholar

[6] Shakhtakhtinsky, T.N., Bakhmanov, M.F. , Kebaliev, G.I. Methods optimizing the processes of chemical technology with computer software. Publishing house Elm, Baku, 1985, p.260.

Google Scholar

[7] All Union State standard GOST 2117-99 Petroleum products. Method for determining the fractional composition.

Google Scholar

[8] All Union State standard GOST 1437-75 Dark oil products. An accelerated method for sulfur determination.

Google Scholar