Thermogravimetric Study on the Co-Pyrolysis Characteristics of Bituminous Coal and Wheat Straw

Abstract:

In this work, the pyrolysis behavior of bituminous coal (BC) wheat straw (WS) and the blends were investigated by thermogravimetric analysis. It was found that the main thermal degradation stage of BC and WS lies in different temperature range and there is nearly no overlapping. Interaction was observed during the co-pyrolysis process of BC and WS. At high temperatures, the volatile releasing is slightly inhibited by WS addition. Coats-Redfern method was used to analyze the apparent kinetic parameters. The results indicated that both the two reaction stages during pyrolysis process are well correlated by first-order reaction. The variation trend of activation energy value further confirm the synergistic effects between BC and WS. The experimental results may provide useful data for co-thermochemical utilization of biomass with coal.

• Periodical: Advanced Materials Research (Volumes 1070-1072)
• Pages: 146-151
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.1070-1072.146
• Online since: December 2014
• Authors: Xin Ping Yan*, Ji Song Bai, Xiong Zhou, Shun Hong Lin
• Keywords: Bituminous Coal, Co-Pyrolysis, Thermogravimetric Analysis, Wheat Straw

References

[1] M. Sami, K. Annamalai, M. Wooldridge. Prog. Energy Combust. Sci. Vol. 27 (2001), p.171–214.

[2] H.B. Vuthaluru. Bioresour. Tech. Vol. 92 (2004), pp.187-195.

[3] E. Kastanaki, D. Vamvuka, P. Grammelis. Fuel Process. Technol. Vol. 77–78 (2002), p.159–160.

[4] P. Yangalia, A.M. Celayaa J.L. Goldfarb. J. Anal. Appl. Pyrol. Vol. 108 (2014), pp.203-211.

[5] H. Haykiri-Acma, S. Yaman. FuelVol. 86 (2007), p.373–380.

[6] A.W. Caots, J.P. Redfern. Nature Vol. 201 (1964), p.68.

[7] Y.S. Lin, X.Q. Ma, Z.S. Yu. Bioresour. Tech. Vol. 166 (2004), pp.444-450.