Study of Phenol Oxidation Products over Glassy Carbon Electrode in Alkaline Solutions by Photoluminescence Spectroscopy

Article Preview

Abstract:

In this research, a new approach is used to identify the products of electrochemical oxidation of UV visible substances over solid electrodes. In order to determine the product of phenol electrooxidation over glassy carbon electrode, the results obtained using voltammetric method and photoluminescence spectroscopy have been compared. It was proved that in an alkaline solution phenol is present in form of phenolate-ion, adsorbing on the surface of glassy carbon electrode, and oxidized to hydroquinone with transfer of two electrons.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

23-28

Citation:

Online since:

February 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Sanitary rules and norms 2. 1. 5. 1315-2003, Russian Federation, Drinking Water. Hygienic requirements for water quality of centralized drinking water supply. Quality Control., Russia, (2003).

Google Scholar

[2] I. Nukatsuka, S. Nakamura, K. Watanabe, K. Ohzeki, Determination of phenol in tap water and river water samples by solid- phase spectrophotometry, Anal. Sci. 16 (2000) 269-273.

DOI: 10.2116/analsci.16.269

Google Scholar

[3] G. Norwitz, A. H. Bardsley, P. N. Keliher, Determination of phenol in the presence of sulfite (sulfur dioxide) by the 4-aminoantipyrine spectro-photometric method, Anal. Chim. Acta, 128 (1981) 251–256.

DOI: 10.1016/s0003-2670(01)84108-8

Google Scholar

[4] T.V. Vorobyov, A.V. Terletskaya, N.F. Kuschevskaya, Standard and uniform method of determining phenol in natural and drinking water and basic directions for their improvement, Chem. Tech. water. 29 (2007) 370-390.

Google Scholar

[5] E. A Podolina, E. N Grosev, O. B Rudakov, Extraction and instrumental methods for determining phenols in condensed matter, Condensed Matter and interphase boundaries, 13 (2011) 72-79.

Google Scholar

[6] MU 08-47/189 Natural water, drinking water, clean technology, treated waste. Measurement the mass concentration of phenol by voltammetry, Russia, Tomsk, (2005).

Google Scholar

[7] Ya.I. Korenman, A.T. Alymova, I.V. Vatutina, Determination of phenol and guaiacol in aqueous solutions using extraction-chromatographic preconcentration, J. Analyt. Chem., 57 (2002) 31-34.

Google Scholar

[8] F. Hakim, β-Cyclodextrin-bonded silica particles as the solid-phase extraction medium for the determination of phenol compounds in water samples followed by gas chromatography with flame ionization and mass spectrometry detection, J. Chromatogr. A, 1087 (2005).

DOI: 10.1016/j.chroma.2005.06.009

Google Scholar

[9] J. Peng, Yu Su, Y. Zhao, B. Hu, S. Hu, Electrochemical behavior of phenol at a glassy carbon electrode modified with acetylene black composite sour digeksadetsilfosfat, vprisutstvii cetyltrimethylammonium bromide, Electrochemistry, 44 (2008).

DOI: 10.1134/s1023193508020079

Google Scholar

[10] W. Huang, D. Zhou, X. Liu, X. Zheng, Electrochemical determination of phenol using ctab-functionalized montmorillonite electrode, Environmental Technology, 30 (2009) 701-706.

DOI: 10.1080/09593330902894364

Google Scholar

[11] I.E. Mülazimoǧlu, E. Yilmaz, Quantitative determination of phenol in natural decayed leaves using procaine modified carbon paste electrode surface by cyclic voltammetry, Desalination. 256 (2010) 64-69.

DOI: 10.1016/j.desal.2010.02.014

Google Scholar

[12] Z. Yongde, M. Jinyuan, The 2. 5th order differential voltammetric determination of phenol with a composite carbon paste/polyamide electrode, Anal. Chim. Acta, 353 (1997) 71-78.

DOI: 10.1016/s0003-2670(97)00340-1

Google Scholar

[13] М. Gattrel, D. Kirk, A study of electrochemical passivation during aqueous phenol electrolysis, J. Electrochem. Soc., 4 (1993) 903-911.

DOI: 10.1149/1.2056225

Google Scholar

[14] L. Hernandez, P. Hernandez, V. Velasco, Carbon felt electrode design: application to phenol electrochemical determination by direct oxidation, Anal. Bioanal. Chem., 377 (2003) 262-266.

DOI: 10.1007/s00216-003-2022-y

Google Scholar

[15] Q. Fulian, R.G. Compton, Laser activated voltammetry: application to the determination of phenol in aqueous solution at a glassy carbon electrode, Analyst, 125 (2000) 31-534.

DOI: 10.1039/a908826a

Google Scholar

[16] Yi. Hongchao, W. Kangbing, H. Shengshui, C. Dafu, Adsorption stripping voltammetry of phenol at Nafion-modified glassy carbon electrode in the presence of surfactants, Talanta, 55 (2001) 1205–1210.

DOI: 10.1016/s0039-9140(01)00531-8

Google Scholar

[17] I.M. Yasnev, O.V. Mustea, E.O. Averyaskina, S.S. Ermakov, Determination of phenol by direct-current coulometry variable counting the total amount of electricity by coulometric constant, Bulletin of the University of St. Petersburg. Series 4: Physics Chemistry, 2012, 115-119.

Google Scholar

[18] K.V. Alekseenko, V.N. Batalova, Development of methodology for measurement of phenol in wastewater by voltammetry and regulatory effluent, Bulletin of the Tomsk State University, 370 (2013) 187-189.

Google Scholar

[19] N.B. Sultimova, D.C. Bazyl, O.N. Tchaikovsky, I.V. Sokolova, V.A. Svetlichny, Influence of heavy atom substitution on the spectral-luminescent properties and photolysis of phenol, Atmos. Ocean Opt., 15 (2001) 258-262.

Google Scholar