Acrylate Hydrogel Modification Using a Cross-Linking Agent for Increasing Multilayer Glazing Flame Resistance

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The design of layers for multilayer flame-resistant glass is a vital task in terms of upgrading fire resistance of window glass units. This paper describes chemical modification of flame-proof acrylate hydrogel layers and shows experimentally how a cross-linking agent — hexamethoxymethylmelamine ether – influences the kinetics of hydrogel polymerization and the enhancement of carbonated structures yield. It has been determined that adding HMMM to the hydrogel composition raises the coke residue yield from 10 % to 35 % and increases the 19 mm thick glass flame resistance class from EI30 to EI50.

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265-269

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February 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Mannan, Hazard Identification, Assessment and Control, Elsevier, (2014).

Google Scholar

[2] Y. Gao, W.K. Chow, M. Wu, Thermal performance of window glass panes in an enclosure fire, Constr. Build. Mater. 47 (2013) 530-546.

DOI: 10.1016/j.conbuildmat.2013.05.027

Google Scholar

[3] World Nanomaterials, Industry study with Forecasts for 2016 & 2021 Study No. 2871, (2012).

Google Scholar

[4] M. Hasanzadeh, N. Shadjou, L. Saghatforoush, R. Mehdizadeh, S. Sanati, Electrocatalytic oxidation of selected parabens on zinc hydroxide nanoparticles, Catal. Commun. 19 (2012) 10-16.

DOI: 10.1016/j.catcom.2011.12.012

Google Scholar

[5] K. Eiichiro, Fireproof protective plate glass with antireflection film, fireproof protective laminated glass with the antireflection film, and specific fire prevention apparatus, JP 2011168472011-09-01 (2011).

Google Scholar

[6] K. Eiichiro, Fireproof safety glass, method for manufacturing the same, fireproof safety glass joined body, fireproof safety glass window structure, and construction method for fireproof safety glass window, JP 2009149486 (2009).

DOI: 10.1520/c0002

Google Scholar

[7] N. Yasuhiko, H. Asahito, Laminated glass, JP 20070096970 (2007).

Google Scholar

[8] I.N. Burmistrov, A.S. Leshchenko, L.G. Panova, Study of cross-linking parameters of polyacrylic acid hydrogels, Russian J. Appl. Chem. 84, 11 (2011) 1920-(1923).

DOI: 10.1134/s1070427211110140

Google Scholar

[9] Yu.S. Egina, I.N. Burmistrov, N.A. Kolesnichenko, L.G. Panova, A study of the polymerisation temperature of hydrogel and the properties of the copolymers synthesized, Int. Polymer Sci. Tech. 36 (2009) 53-56.

DOI: 10.1177/0307174x0903600414

Google Scholar