Synthesis and Properties of Functionalized Sulfur-Containing Hexa-Peri-Hexabenzocoronene

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Abstract:

Synthesis and characterization of a novel hexabenzocoronene (HBC) derivative attached with four alkyl swallow-tailed chains and two sulfur-containing chains are described. The designed peripheral decoration with dove tails as solubilizer and sulfur-containing groups as functionalizer is expected to improve the solubility of molecules, change the columnar spacing stacks and make for its orientation on matrix surface. Its UV−vis absorption spectra appeared in 350-400 nm region as same as typical that of this kind of compounds. The thermal properties as discotic liquid crystal and its orientation on matrix are being studied.

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290-294

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February 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Sinnokrot, M. O., Sherrill, C. D., J. Am. Chem. Soc. 126 (2004) 7690-7697.

Google Scholar

[2] Tengzhou Yang, Jialing Pu, Jun Zhang, Wenguang Wang, J. Org. Chem. 78 (2013) 4857−4866.

Google Scholar

[3] Dimitrakopoulos, C. D., Malenfant, P. R. L., Adv. Mater. 14 (2002) 99-117.

Google Scholar

[4] O'Neill, M., Kelly, S. M., Adv. Mater. 15 (2003) 1135-1146.

Google Scholar

[5] Pisula, W., Menon, A., Stepputat, M., Lieberwirth, I., Kolb, U., Tracz, A., Sirringhaus, H., Pakula, T., Müllen, K., Adv. Mater. 17 (2005) 684-689.

DOI: 10.1002/adma.200401171

Google Scholar

[6] Wang, Z., Dötz, F., Enkelmann, V., Müllen, K., Angew. Chem. Int. Ed. 44 (2005) 1247-1250.

Google Scholar

[7] Rui Cheng, Wenguang Wang, Tengzhou Yang, Yu Jiang, Jialing Pu, Advanced Materials Research. 554-556 (2012) 43-46.

Google Scholar

[8] Yu Jiang, Xuying Liu, Rui Cheng, Wenguang Wang, Jialing Pu, Solid State Phenomena. 181-182 (2012) 173-176.

Google Scholar

[9] Warman, J. M., deHaas, M. P., Dicker, G., Grozema, F. C., Piris, J., Debije, M. G., Chem. Mater. 16 (2004) 4600-4609.

Google Scholar

[10] M.S. Yusubov., Galina A., Tetrahedron. 58 (2002) 1607-1610.

Google Scholar

[11] ShunjiIto, MikeWehmeier, J. Diedrich Brand., Chem. Eur. J. 23 (2000) 4327-4342.

Google Scholar

[12] Abdelwareth, A. O. Sarhan, Carsten Bolm, Chem. Soc. Rev. 38 (2009) 2730–2744.

Google Scholar

[13] S.P. Brown, I. Schnell, J.D. Brand, K. Müllen, H.W. Spiess, J. Am. Chem. Soc. 121(1999)6712-6718.

Google Scholar