The Utilization of Phenol Components in Bio-Oil for Modifying Urea-Formaldehyde Resin Adhesive

Article Preview

Abstract:

The components in bio-oil are mainly concluding organic acid, aldehydes and phenolics. As the irregular cracking of the pyrolysis, the products are complex and difficult to separate. A comprehensive concept was presented and the extractions from bio-oil were used for modifying urea-formaldehyde (UF) resin in this study. Characterization by FT-IR and GC-MS indicated that the reaction mechanism. Phenol-oil addition amount and particle boards test were investigated resulted those 10% phenol-oil shows the best properties: viscosity of 73.36 mm/s, solid content of 52.25% and pH of 8.35 and the best pressing condition is 125°C for 5min which produce a 1.23MPa bond strengthen and 1.05 mg/L formaldehyde emission plywood.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

209-213

Citation:

Online since:

April 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Bulushev D A, Ross J R H. Catalysis for conversion of biomass to fuels via pyrolysis and gasification: a review[J]. Catalysis Today, 2011, 171(1): 1-13.

DOI: 10.1016/j.cattod.2011.02.005

Google Scholar

[2] Demirbas A. The influence of temperature on the yields of compounds existing in bio-oils obtained from biomass samples via pyrolysis[J]. Fuel Processing Technology, 2007, 88(6): 591-597.

DOI: 10.1016/j.fuproc.2007.01.010

Google Scholar

[3] De Wild P, Den Uil H, Reith H, et al. Hybrid Staged Degasification[J]. International Journal of Chemical Reactor Engineering, 2009, 7: A51.

Google Scholar

[4] Mullen C A, Boateng A A. Chemical composition of bio-oils produced by fast pyrolysis of two energy crops[J]. Energy & fuels, 2008, 22(3): 2104-2109.

DOI: 10.1021/ef700776w

Google Scholar

[5] Ingram L, Mohan D, Bricka M, et al. Pyrolysis of wood and bark in an auger reactor: physical properties and chemical analysis of the produced bio-oils[J]. Energy & Fuels, 2007, 22(1): 614-625.

DOI: 10.1021/ef700335k

Google Scholar

[6] Black S K, Chum H L, Diebold J P, et al. Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials: U.S. Patent 5, 235, 021[P].

Google Scholar

[7] Kelley S S, Wang X M, Myers M D, et al. Use of biomass pyrolysis oils for preparation of modified phenol formaldehyde resins[M] Developments in Thermochemical Biomass Conversion. Springer Netherlands, 1997: 557-572.

DOI: 10.1007/978-94-009-1559-6_44

Google Scholar

[8] Gagnon M, Roy C, Riedl B. Adhesives made from isocyanates and pyrolysis oils for wood composites[J]. Holzforschung, 2004, 58(4): 400-407.

DOI: 10.1515/hf.2004.060

Google Scholar

[9] Tian Q K, He L, Zhang H, et al. Study on Solvent Extraction of Fast Pyrolysis Bio-Oil[J]. Advanced Materials Research, 2011, 306: 1532-1536.

DOI: 10.4028/www.scientific.net/amr.306-307.1532

Google Scholar

[10] Czernik S, Bridgwater A V. Overview of applications of biomass fast pyrolysis oil[J]. Energy & Fuels, 2004, 18(2): 590-598.

DOI: 10.1021/ef034067u

Google Scholar