The Properties of Polyetheretherketone Biocomposite Reinforced by Surface-Modified Nano-Hydroxyapatite

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In order to improve the mechanical properties of HA/PEEK composite, the surface modification of nanosized hydroxyapatite (n-HA) was carried out with silane coupling agent (SCA).The modified particles were produced using different contents of SCA (KH560) and characterized by virtue of Fourier Transform Infrared (FT-IR) spectroscopy. The polyetheretherketone (PEEK) nanocomposite materials reinforced by surface-modified n-HA were successfully prepared and their microstructure and mechanical properties were examined by scanning electron microscopy (SEM), Instron IX Material Testing System and Vickers micro-hardness tester. The result of FT-IR indicated that the nanosized HA was coupled with the SCA by a chemical bonding. SEM observation showed that SCA-HA was well-dispersed in PEEK matrix. The results incicated that mechanical strength of SCA-HA/PEEK composite was improved and best at 5 vol.% HA, 3wt.% SCA.Keywords: nanosized hydroxyapatite; Silane couping agent; Polyetheretherketone; Biocomposite; Mechanical propertity

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214-218

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April 2015

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[1] R. Langer, J.P. Vacanti, Tissue engineering, Science. 260 (1993) 920-6.

Google Scholar

[2] A.J. Salgada, O.P. Coutinho, R.L. Reis, Bone tissue engineering: state of the art and future trends. Macromol Biosci. 4 (2004) 743-65.

DOI: 10.1002/mabi.200400026

Google Scholar

[3] S.M. Kurtz, J.N. Devine, PEEK biomaterials in trauma, orthopedic, and spinal implants, Biomaterials. 28(32) (2007) 4845-69.

DOI: 10.1016/j.biomaterials.2007.07.013

Google Scholar

[4] Y.C. Chou, D.C. Chen, W.A. Hsieh, W.F. Chen, P.S. Yen, T. Harnod, T.L. Chiou, Y.L. Chang, C.F. Su, S.Z. Lin, S.Y. Chen, Efficacy of anterior cervical fusion: comparison of titanium cages, polyetheretherketone (PEEK) cages and autogenous bone grafts, Journal of Clinical Neuroscience. 15(11) (2008).

DOI: 10.1016/j.jocn.2007.05.016

Google Scholar

[5] K Fujihara, Z.M. Huang, S. Ramakrishna, K. Satknanantham, H. Hamada, Performance study of braided carbon/PEEK composite compression bone plates, Biomaterials. 24(15) (2003) 2661-7.

DOI: 10.1016/s0142-9612(03)00065-6

Google Scholar

[6] M.S. Abu Bakar, M.H.W. Cheng, S.M. Tang, S.C. Yu, K Liao, C.T. Tan, Tensile properties, tension-tension fatigue and biological response of polyetheretherketone-hydroxyapatite composites for load-bearing orthopedic implants, Biomaterials. 24 (2003).

DOI: 10.1016/s0142-9612(03)00028-0

Google Scholar

[7] S. Yu, K.P. Hariram, R. Kumar, P. Cheang, K.K. Aik, In vitro apatite formation and its growth kinetics on hydroxyapatite/polyetheretherketone biocomposites, Biomaterials. 26(15) (2005) 2343-52.

DOI: 10.1016/j.biomaterials.2004.07.028

Google Scholar

[8] L. Wang, L.Q. Weng, S.H. Song, Z.Y. Zhang, S.L. Tian, R. Ma, Characterization of polyetheretherketone-hydroxyapatite nanocomposite materials, Materials Science and Engineering A. 528 (2011) 3689-96.

DOI: 10.1016/j.msea.2011.01.064

Google Scholar

[9] L. Wang, L.Q. Weng , S.H. Song, Q.J. Sun, Mechanical properties and microstructure of polyetheretherketone-hydroxyapatite nanocomposite materials, Materials Letters. 64 (2010) 2201-4.

DOI: 10.1016/j.matlet.2010.06.067

Google Scholar

[10] L. Wang, L.Q. Weng , L.L. Wang S.H. Song, Hydrothermal synthesis of hydroxyapatite nanoparticles with various counterions as templates, Journal of the Ceramic Society of Japan. 118(12) (2010) 1195-8.

DOI: 10.2109/jcersj2.118.1195

Google Scholar

[11] J.T. Liao, X.J. Wang, Y. Zuo, L. Zhang, J.Q. Wen, Y.B. Li, Surface modification of nano-hydroxyapatite with silane agent, Journal of Inorganic Materials. 23(1) (2008) 145-9.

DOI: 10.3724/sp.j.1077.2008.00145

Google Scholar

[12] H.C. Dai, Study on the modification of Silica an Properties of Composites formed by the Silica and Polymer, thesis (2002).

Google Scholar

[13] Y.H. Lai, M.C. Kuo, J.C. Huang, M. Chen, On the PEEK composites reinforced by surface-modified nano-silica, Materials Science and Engineering A. 458 (1-2) (2007) 158-69.

DOI: 10.1016/j.msea.2007.01.085

Google Scholar