Quantitative Calculation of Polynuclear Aluminum Content in the Forced Hydrolysis-Polymerization Course of Aluminum (III) Salt Solutions

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Abstract:

According to the results of potentiometric titration of aluminum salt solutions under the moderate slow rate of injecting base and the three critical feature points on its titration curves, at the same time, using the self-contained Boltzmann's equation of Origin software fitting the curve, the quantitative formula of poly-aluminum content have been given. This formula can calculate conveniently the polynuclear aluminum content in the forced hydrolysis-polymerization process. The value of pattern calculation coincides with that of the Al-ferron timed spectrophotometry assay, which offers a kind of new method for studying the course and the quantitative determination of Al (III) salt solutions in simple water systems.

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351-355

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] H.X. Tang: Huanjing Kexue xuebao(Acta Scientiae Circumstantiae, In Chinese) Vol. 18 (1998), p.1.

Google Scholar

[2] H.R. Maier, N. Morgan, C.W.K. Chow: Environmental Modelling & Software Vol. 19(2004), p.485.

Google Scholar

[3] R.W. Smith: ACS, Advances in Chem. Series Vol. 106(1971), p.250.

Google Scholar

[4] J.W. Akitt, W.N. Greenwood, S.G. Lester: J. Chem. Soc. Vol. 1968(1968), p.803.

Google Scholar

[5] C.Y. Wang, , S.P. Bi, , M.B. Luo: Review in Analytical Chemistry Vol. 22(2003), p.53.

Google Scholar

[6] S.J. Duffy, G.W. Vanloon: Environ Sci & Technol. Vol. 28(1994), p.1950.

Google Scholar

[7] C.Y. Wang, C.H. Zhang, S.P. Bi: Spectroscopy and Spectral Analysis Vol. 25(2005), p.252.

Google Scholar

[8] R.J. Stol, A.K. van Helden, P.L. Bruyn: J. Colloid Interface Sci., Vol. 57(1976), p.115.

Google Scholar

[9] J.L. Bersillon, P.H. Hsu, F. Flessinger: Soil Sci. Soc. Am. J. Vol. 44(1980), P630.

Google Scholar

[10] B.L. Phillips, W.H. Casey, M. Karlsson: Nature Vol. 404 (2000), p.379.

Google Scholar

[11] C.Y. Wang, Z. P. Han, P. Wang: Bull. Chem. Soc. Ethiop. Vol. 22(2008), p.155.

Google Scholar

[12] S.P. Bi, C.Y. Wang, Q. Cao, C.H. Zhang: Coordination Chemistry Reviews Vol. 248(2004), p.441.

Google Scholar

[13] H.M. Irving, M.G. Miles, L.D. Pettit: Anal. Chim. Acta. Vol. 38(1967), p.475.

Google Scholar

[14] H.Z. Zhao, Z.K. Luan, Y.B. Su: Chemical Journal of Chinese Universities Vol. 23(2002), 751.

Google Scholar

[15] H. Hek, R.J. Stol, P.L. Bruyn: J. Colloid and Interface Science Vol. 64(1978), p.72.

Google Scholar

[16] R.D. Letterman, S.R. Asolekar: Wat. Res. Vol. 24(1990), p.931.

Google Scholar

[17] P.M. Bertsch, D.R. Parker: Aqueous polynuclear aluminum species, In The Environmental Chemistry of Aluminum (Lewis Publishers, New York, 1996).

Google Scholar