Potentiodynamic Polarization Studies of Glycerin in Platinum Electrodes

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A three electrode system was used for the analysis of potentiodynamic polarization studies of glycerin in platinum electrodes. Particular attention was devoted to the estimation of diffusion coefficient of glycerin in platinum electrodes by the use of electrochemical techniques such as the sweep of the potential. Cyclic voltammograms were recorded at different sweep rates (0.01 and 0.07 V·s-1). Randles-Sevcik equation was taken into consideration and a linear relationship was found between the peak current and the square root of the voltage sweep rate from where the value of diffusion coefficient could be determined. The values of Tafel constants, useful in the understanding of electrochemical reaction kinetics are also reported in the present paper.

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348-351

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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