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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1105Synthesis and Characterization of Modified...

Synthesis and Characterization of Modified Polydimethylsiloxane Nanomembrane for Chiral Separation

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Abstract:

Polydimethylsiloxane-2-[2-tert-Butoxycarbonylamino-(1H-pyrazol-4-yl)-propionylamino] -3-phenyl-propanoic acid (PDMS-BCPA) is a newly developed stereo-specific membrane that interacts with S configuration of enantiomers as chiral recognition sites. In this study, realization of PDMS-BCPA nanomembrane was achieved via anodized aluminum oxide (AAO) template synthesis approach followed by the attachment of synthesized chiral selector (BCPA) using simple immersion method. The effect of surface modification and the attachment with chiral selector were investigated and characterized using Fourier Transform Infrared spectroscopy (FT-IR), Field Emission Scanning Electron Microscopic (FE-SEM) and Atomic Force Microscopic (AFM) methods. The characterization via these methods indicates the synthesized BCPA as chiral selector was successfully attached onto the PDMS surface. The enantioselectivity of PDMS-BCPA nanomembrane was verified by the separation of alpha cypermethrin enantiomer.

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Membranes and Membrane Technologies

Advanced Materials Research V

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Periodical:

Advanced Materials Research (Volume 1105)

Pages:

231-236

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1105.231

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Online since:

May 2015

Authors:

Non Daina Masdar, Abdul Hadi Mahmud, Mohd Tajudin Mohd Ali, Syarifah Nursyimi Azlina Syed Ismail, Ruziyati Tajuddin, Norashikin Saim, Abd Mutalib Md Jani

Keywords:

AAO, Chiral Extraction, Chiral Selector, Nanomembrane, PDMS

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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