Optical Properties of [(TeO2)0.7 (B2O3)0.3]1-x (Bi2O3)x Glass System

Azuraida Amat; Mohamed Kamari Halimah; Nurazlin Ahmad

doi:10.4028/www.scientific.net/AMR.1107.426

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1107Optical Properties of [(TeO2)0.7 (B2O3)0.3]1-x...

Optical Properties of [(TeO₂)_0.7(B₂O₃)_0.3]_1-x (Bi₂O₃)_x Glass System

Abstract:

Ternary tellurite based glasses [(TeO₂)_0.7(B₂O₃)_0.3]_1-x (Bi₂O₃)_x was prepared by melt quenching method with suitable melting and quenching temperature. A series of glasses were selected from 0.05 to 0.30 mol % and its glass-forming region was determined. The density, molar volume and refractive index increase when bismuth ions Bi³⁺ increase, this is due to the increased polarization of the ions Bi³⁺ and the enhanced formation of non-bridging oxygen (NBO). The values of optical band gap, E_opt decreases when Bi₂O₃ content increases. Urbach energy for each composition was also calculated and was found to be dependent on the glass composition.

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Advanced Materials Research (Volume 1107)

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426-431

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https://doi.org/10.4028/www.scientific.net/AMR.1107.426

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June 2015

Authors:

Azuraida Amat, Mohamed Kamari Halimah*, Nurazlin Ahmad

Keywords:

Bismuth, Boro-Tellurite, Optical Property

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