Green Synthesis of Silver Nanoparticles Using Elaeis Guineensis from Palm Leaves: Influence of pH in Reaction Kinetic

Article Preview

Abstract:

In this research, green synthesis of silver nanoparticles using elaeis guineensis leaves extract was investigated and the influence of pH and reaction time in the reaction kinetic were studied. UV-visible spectrophotometer was used to monitor the reduction reaction of silver ions to silver nanoparticles and formation of silver nanoparticles shown at sharp peak at pH 10 with λmax of 391 nm. Transmission electron microscopy (TEM) shows silver nanoparticles are polydispersed and irregular shape with size ranging from 55-85 nm. Formation of silver nanoparticles was confirmed by energy dispersive x-ray analysis (EDAX) and crystalline structure using XRD. From this research, it was found that pH 10 influenced the reaction kinetic therefore reduce the reaction time.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

560-565

Citation:

Online since:

July 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Vanaja, S. Rajeshkumar, K. Paulkumar, G. Gnanajobitha, C. Malarkodi, and G. Annadurai*, Kinetic study on green synthesis of silver nanoparticles using coleus aromaticus leaf extract, Advanced in Applied Science Research vol. 4, pp.50-55, (2013).

DOI: 10.1155/2013/317963

Google Scholar

[2] E. Elumalai, T.N.V.K.V. Prasad, V. Kambala, P.C. Nagajyothi, and E. David, Green synthesis of silver nanoparticle using Euphorbia hirta L and their antifungal activities, Archives of Applied Science Research, vol. 2, pp.76-81, (2010).

Google Scholar

[3] C. Panneerselvam, S. Ponarulselvam, and K. Murugan, Potential Anti-plasmodial Activity of Synthesized Silver nanoparticles using Andrographis paniculata Nees (Acanthaceae), Archives of Applied Science Research, vol. 3, pp.208-217, (2011).

Google Scholar

[4] U. Kreibig and M. Vollmer, Materials Mix. Optical properties of metal clusters, Springer: Berlin, vol. 25, p.532, (1995).

Google Scholar

[5] T. Wang, M. Kaempgen, P. Nopphawan, G. Wee, S. Mhaisalkar, and M. Srinivasan, Silver nanoparticle-decorated carbon nanotubes as bifunctional gas-diffusion electrodes for zinc-air batteries, Journal of Power Sources, vol. 195, pp.4350-4355, (2010).

DOI: 10.1016/j.jpowsour.2009.12.137

Google Scholar

[6] R. W. -Y. Sun, R. Chen, N. P. -Y. Chung, C. -M. Ho, C. -L. S. Lin, and C. -M. Che, Silver nanoparticles fabricated in Hepes buffer exhibit cytoprotective activities toward HIV-1 infected cells , Chem. Commun, p.5059, (2005).

DOI: 10.1039/b510984a

Google Scholar

[7] A. Kumar, P. K. Vemula, P. M. Ajayan, and G. John, Silver-nanoparticle-embedded antimicrobial paints based on vegetable oil, Nat Mater, vol. 7, pp.236-41, Mar (2008).

DOI: 10.1038/nmat2099

Google Scholar

[8] R. A. Khaydarov, R. R. Khaydarov, O. Gapurova, Y. Estrin, and T. Scheper, Electrochemical method for the synthesis of silver nanoparticles, Journal of Nanoparticle Research, vol. 11, pp.1193-1200, (2008).

DOI: 10.1007/s11051-008-9513-x

Google Scholar

[9] C. J. Murphy, A. M. Gole, S. E. Hunyadi, J. W. Stone, P. N. Sisco, A. Alkilany, et al., Chemical sensing and imaging with metallic nanorods, Chem Commun (Camb), pp.544-57, Feb 7 (2008).

DOI: 10.1039/b711069c

Google Scholar

[10] L. Christensen, S. Vivekanandhan, M. Misra, and A. K. Mohanty, Biosynthesis of silver nanoparticles using murraya koenigii (curry leaf): An investigation od the effect of broth concentration inreduction mechanism and particles size , ADVANCED MATERIALS vol. 2, pp.429-434, (2011).

DOI: 10.5185/amlett.2011.4256

Google Scholar

[11] Sumit.S. Lal and P.L. Nayak, Green synthesis of gold nanoparticles using various extract of plants and spices, Review Journal For Science vol. 2, pp.325-350, (2012).

Google Scholar

[12] N. A. Arham, N. A. N. Mohamad, J. Jai, J. Krishnan, and N. M. Yusof, Application of Response Surface Methodology in Extraction of Bioactive Component from Palm Leaves (Elaeis guineensis), vol. 5, (2013).

DOI: 10.12777/ijse.5.2.95-100

Google Scholar

[13] D. Philip, Spectrochimica Acta Part A, vol. 78, p.327–331, (2011).

Google Scholar

[14] M. Vanaja, G. Gnanajobitha, K. Paulkumar, S. Rajeshkumar, C. Malarkodi, and G. Annadurai, Phytosynthesis of silver nanoparticles by cissus quadrangularis influence of physicochemical factors, Nanostructure in Chemistry, vol. 3, (2013).

DOI: 10.1186/2193-8865-3-17

Google Scholar