Thermal Property of Eutectic Molten Salts by Using Thermogravimetric Analyzer (TGA)

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Abstract:

The thermal property of new composition of eutectic molten salt was investigated to obtain low melting point and better stability at temperature of 500°C as heat transfer fluid in solar thermal energy system. The NaCl used was purified from seawater. The eutectic molten salts were prepared in ten different weight ratios and experiments were carried out using nitrogen as inert gas with heating of 10°C/min to the temperature from 25°C to 500°C. Experimental results indicated that all mixtures exhibited low melting point (<163°C) and high stability. The thermal degradation of LiNO3, NaNO3, KNO3 and NaCl exhibit in the DTG profiles respectively. From the present study it can be concluded that major weight loss of the system is due to the dissociation of lithium nitrate to lithium oxides.

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611-614

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July 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] D. E. Meeker, R. B. (1990). High-temperature stability of ternary nitrate molten salts for solar thermal energy systems. Solar Energy Materials, 21, 51-60.

DOI: 10.1016/0165-1633(90)90042-y

Google Scholar

[2] T. Wang, D. M. (2012). Thermal stability of the euctectic composition in LiNO3-NaNO3-KNO3 ternary system used for thermal energy storage. Solar Energy Materials & Solar Cells, 162-168.

DOI: 10.1016/j.solmat.2012.01.009

Google Scholar

[3] Coscia, K., Elliot, T., Mohapatra, S., Oztekin, A., and Neti, S. (2013). Binary and Ternary Nitrate Solar Heat Transfer, Journal of Solar Energy Engineering 135 (2).

DOI: 10.1115/1.4023026

Google Scholar

[4] R. Devaradjane. (2013). Utilization of molten nitrate salt nanomaterials for heat capacity enhancement in solar power applications, Proquest LLC, 56.

Google Scholar

[5] D. Kearney, U. H. (2003). Assessment of a molten salt heat transfer fluid in a parabolic trough solar field. Journal of Solar Energy Engineering, 125, 170-176.

DOI: 10.1115/1.1565087

Google Scholar

[6] S. Munir, S. S. Daood, W. Nimmo, A. M. Cunliffe, B. M. Gibbs, (2009). Thermal analysis and devolatilization kinetics of cotton stalk, sugar cane bagasse and shea meal under nitrogen and air atmospheres. Bioresource Technology 3, 1413–1418.

DOI: 10.1016/j.biortech.2008.07.065

Google Scholar

[7] T. Bauer, D. Laing, & R. Tamme, (2011). Recent Progress in Alkali Nitrate/Nitrite Developments. Molten Salts Chemistry and Technology, MS9, 1-10.

DOI: 10.1002/9781118448847.ch7c

Google Scholar