Synthesis and Characteristic of Borazine-Silicon-Containing Arylacetylene Resin

Chao Zhou; Kang Kang Guo; Hui Min Qi; Ya Ping Zhu; Fan Wang

doi:10.4028/www.scientific.net/AMR.1120-1121.550

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1120-1121Synthesis and Characteristic of...

Synthesis and Characteristic of Borazine-Silicon-Containing Arylacetylene Resin

Abstract:

Borazine-silicon-containing arylacetylene (PBZSA) resin was a novel organic inorganic hybrid polymer and prepared through condensation reaction among B,B’,B’’-trichloroborazine, dichlorosilane and arylacetylene Grignard reagent. The chemical structure of PBZSA resin was characterized by FT-IR and ¹H NMR. The thermal stability and dielectric properties of cured PBZSA were investigated by TGA and broadband dielectric spectrometer. The results indicated that cured PBZSA showed high thermal stability with char yield up to 87.1% at 1000°C and at decompose temperature (T_d5) 580°C, and low dielectric constant (2.8-2.9) and dielectric loss (<0.005).

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Periodical:

Advanced Materials Research (Volumes 1120-1121)

Pages:

550-553

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1120-1121.550

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Online since:

July 2015

Authors:

Chao Zhou, Kang Kang Guo, Hui Min Qi*, Ya Ping Zhu, Fan Wang

Keywords:

Arylacetylene, Borazine, Dielectric, Thermal

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