Friedel-Crafts Acylation of Anisole Catalyzed by Green, Reusable Hydroxyapatite-Zinc Bromide Catalyst

Ben Mei Wei; Zhi Yong Zhang; Zhi Qun Dai

doi:10.4028/www.scientific.net/AMR.113-116.18

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Friedel-Crafts Acylation of Anisole Catalyzed by Green, Reusable Hydroxyapatite-Zinc Bromide Catalyst
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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 113-116Friedel-Crafts Acylation of Anisole Catalyzed by...

Friedel-Crafts Acylation of Anisole Catalyzed by Green, Reusable Hydroxyapatite-Zinc Bromide Catalyst

Abstract:

This study was aimed at the development of a green and reusable catalyst for Friedel-Crafts acylation. Firstly, Hydroxyapatite (HAP) and Hydroxyapatite-zinc bromide (HAP-ZnBr2) have been prepared by the co-precipatation method and hydrothermal method respectively. Their structures were characterized by X-ray Diffraction (XRD), Brunauer-Emmett-Teller (BET) and Infrared Spectroscopy (IR). The catalytic efficiency of HAP-ZnBr2 was examined for Friedel-Crafts acylation of anisole. The results showed that the catalyst was green, high activity, high selectivity and it could be reused at least 5 times without obvious activity loss.

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Periodical:

Advanced Materials Research (Volumes 113-116)

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18-21

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.113-116.18

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Online since:

June 2010

Authors:

Ben Mei Wei, Zhi Yong Zhang, Zhi Qun Dai

Keywords:

Anisole, Catalyzed, Friedel-Crafts Arylation, Hydroxyapatite-Zinc Bromide

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