Fluoride Toxicity in Bioleaching of Fluorapatite

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The use of biohydrometallurgical processes may be restricted by microbial inhibition due to inhibiting fluoride originating from the feed material. In this work, phosphorus bioleaching experiments on fluorapatite ore were conducted in a reactor using Fe-and S-oxidizing bacteria, resulting in 56 % leaching yield for P, despite abundant (800 mg l-1) F in the pregnant leach solution. In further F toxicity experiments it was observed that aluminum had a significant role in decreasing the inhibition caused by F, by producing stable complexes with Al. The bioleached ore contained plenty of Al, explaining why bioleaching was not strongly inhibited.

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406-409

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November 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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