Paper Titles

Capillary Force-Aided Gas Hydrate Growth in Shut-In Conditions
p.619

Failure Criteria and its Application in Wellbore Studies
p.624

Leaching and Kinetic Modeling of Malaysian Low Grade Manganese Ore in Sulfuric Acids
p.629

Advances in Evaluation of Surfactant Performances at High Temperature by Static Foam Tests
p.634

The Presence of Additive Mixtures (THF/SDS) on Carbon Dioxide Rich Gas Mixture Hydrate Formation and Dissociation Conditions
p.639

The Utilization of Recycled Newspaper in the Production of Cellulose Microfiber
p.644

Preliminary Study on the Synthesis of ZIF-8 Membranes via In Situ and Secondary Seeded Growth Methods
p.649

Parametric Study on the Heating Values of Products as via Steam Gasification of Palm Waste Using CaO as Sorbent Material
p.654

Volumetric Properties of Alkali Salt in Aqueous 1-Butyl-3-Methylimidazolium Tetrafluoroborate at Various Temperatures
p.659

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 1133The Presence of Additive Mixtures (THF/SDS) on...

The Presence of Additive Mixtures (THF/SDS) on Carbon Dioxide Rich Gas Mixture Hydrate Formation and Dissociation Conditions

Article Preview

Abstract:

Besides other application of clathrate hydrates, hydrate-based CO₂ capture and storage are potentially important where additives are commonly used to speed up the hydrate formation processes in order to gain on scientific, technological and economic interest. In this work combination of additives such as tetrahydrofuran and sodium dodecyl sulphate (THF/SDS) on mixed gas hydrate formation and dissociation condition have been investigated using a graphical method. The measurements were carried out at temperature and pressure range of (265 to 300) K and (1 to 5) MPa. The presence of additive 3 mol % THF has drastically increased in the hydrate stability region while with the combination of SDS + THF lower the hydrate equilibrium temperature marginally.

You might also be interested in these eBooks

2nd Advanced Materials Conference 2014

Info:

Periodical:

Advanced Materials Research (Volume 1133)

Pages:

639-643

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1133.639

Citation:

Cite this paper

Online since:

January 2016

Authors:

Qazi Nasir*, Bhajan Lal, Lau Kok Keong

Keywords:

CO₂ Rich Gas Mixture, Gas Hydrate, SDS, THF

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] E.D.J. Sloan, C. Koh, Clathrate hydrate of natural gases, 3rd ed., CRC Press, Boca Raton, FL, (2008).

[2] J.P. Osegovic, H.J. P, S.R. Tatro, M.D. Max, On-site freshwater production for offshore facilities, Proceedings in: SPE International Symposium on Oilfield Chemistry 2007. (2007) 431-433.

DOI: 10.2118/106197-ms

[3] A. Delahaye, L. Fournaison, S. Marinhas, I. Chatti, J.P. Petitet, D. Dalmazzone, W. Fürst, Effect of THF on equilibrium pressure and dissociation enthalpy of CO2 hydrates applied to secondary refrigeration, Industrial and Engineering Chemistry Research. 45 (2006).

DOI: 10.1021/ie050356p

[4] I. Chatti, A. Delahaye, L. Fournaison, J.P. Petitet, Benefits and drawbacks of clathrate hydrates: A review of their areas of interest, Energy Conversion and Management. 46 (2005) 1333-1343.

DOI: 10.1016/j.enconman.2004.06.032

[5] Y. Zhong, R.E. Rogers, Surfactant effects on gas hydrate formation, Chem. Eng. Sci. 55 (2000) 4175-4187.

DOI: 10.1016/s0009-2509(00)00072-5

[6] A.H. Mohammadi, B. Tohidi, R.W. Burgass, Equilibrium data and thermodynamic modeling of nitrogen, oxygen, and air clathrate hydrates, Chem. Eng. Data. 48 (2003) 612-616.

DOI: 10.1021/je025608x

[7] Q. Nasir, K.M. Sabil, K. Nasrifar, Measurement and phase behaviour modeling (Dew point + bubble point) of CO2 rich gas mixture, Journal of Applied Sciences. 14 (2014) 1061-1066.

DOI: 10.3923/jas.2014.1061.1066

[8] K.M. Sabil, Q. Nasir, B. Partoon, A.A. Seman, Measurement of H–LW–V and dissociation enthalpy of carbon dioxide rich synthetic natural gas mixtures, Journal of Chemical & Engineering Data. 59 (2014) 3502-3509.

DOI: 10.1021/je500453j

[9] B. Tohidi, A. Danesh, A.C. Todd, R.W. Burgass, K.K. Ostergaard, Equilibrium data and thermodynamic modelling of cyclopentane and neopentane hydrates, Fluid Phase Equilib. 138 (1997) 241-250.

DOI: 10.1016/s0378-3812(97)00164-7

[10] D.B. Robinson, Hydrates in the propane, carbon dioxide and water system, J. Can. Petro. Tech. 10 (1) (1971) 10-35.

[11] A. H. Mohammadi, R. Anderson, B. Tohidi, Carbon monoxide clathrate hydrates: experimental equilibrium data and thermodynamic modeling, AIChE J. 51 (2005) 2833.

DOI: 10.1002/aic.10526

[12] A. Hachikubo, Miyamoto, Atsushi, Hyakutake, Kinji, K. Abe, H. Shoji, Phase Equilibrium Studies on Gas Hydrates Formed from Various Guest Molecules and Powder Ice. In: The Fourth International Conference on Gas Hydrates, Yokohama, Japan, 2002, pp.357-360.

[13] K.M.W. Sabil, G.J. Peters, Phase equilibria of mixed carbon dioxide and tetrahydrofuran hydrates in sodium chloride aqueous solutions, Fluid Phase Equilibria. 284 (2009) 38-43.

DOI: 10.1016/j.fluid.2009.06.006

[14] H.J. Shin Lee Y.J. Im, Y.H. Han, K.W. Lee, J.W. Lee,Y. Lee, J.D. Jang, W.Y. Yoon, Thermodynamic stability, spectroscopic identification and cage occupation of binary CO2 clathrate hydrates, Chem. Eng. Sci, 64 (2009) 5125-5130.

DOI: 10.1016/j.ces.2009.08.019

[15] J. Tang, D. Zeng, C. Wang, Y. Chen, L. He, N. Cai, Study on the infulence of SDS and THF on hydrate-based gas separation performance, Chem Engineering Research and Design. 91 (2013) 1777-1782.

DOI: 10.1016/j.cherd.2013.03.013